A quantum dot is a semiconductor nanostructure that confines the motion of conduction band electrons, valence band holes, or excitons (bound pairs of conduction band electrons and valence band holes) in all three spatial directions.
The confinement can be due to electrostatic potentials (generated by external electrodes, doping, strain, impurities), the presence of an interface between different semiconductor materials (e.g.
in core-shell nanocrystal systems), the presence of the semiconductor surface (e.g.
semiconductor nanocrystal), or a combination of these.
A quantum dot has a discrete quantized energy spectrum.
The corresponding wave functions are spatially localized within the quantum dot, but extend over many periods of the crystal lattice.
A quantum dot contains a small finite number (of the order of 1-100) of conduction band electrons, valence band holes, or excitons, i.e., a finite number of elementary electric charges. Small quantum dots, such as colloidal semiconductor nanocrystals, can be as small as 2 to 10 nanometers, corresponding to 10 to 50 atoms in diameter and a total of 100 to 100,000 atoms within the quantum dot volume.
Self-assembled quantum dots are typically between 10 and 50 nm in size.
Quantum dots defined by lithographically patterned gate electrodes, or by etching on two-dimensional electron gases in semiconductor heterostructures can have lateral dimensions exceeding 100 nm.
At 10 nm in diameter, nearly 3 million quantum dots could be lined up end to end and fit within the width of a human thumb.
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