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Novel water-removal technique boosts performance of carbon nanomaterials

Date:
March 23, 2016
Source:
Los Alamos National Laboratory
Summary:
New research illuminating water’s critical role in forming catalysts for oxygen reduction in materials has revealed the key to designing next-generation carbon nanomaterials with enhanced performance for fuel cells and batteries.
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New research illuminating water's critical role in forming catalysts for oxygen reduction in materials has revealed the key to designing next-generation carbon nanomaterials with enhanced performance for fuel cells and batteries.

"The implications of understanding water's role in achieving high-performance layered materials for energy generation and storage devices will be transformational," said Gautam Gupta of the Materials Synthesis and Integrated Devices group at Los Alamos National Laboratory. A Los Alamos-led team made the discovery.

Limitations on fossil fuels and the increasing demand on energy resources, combined with growing environmental concerns, have made the development of clean and sustainable energy, such as cheap and efficient fuel cells and metal-air batteries, more important than ever.

This research provides the first comprehensive understanding of water's role within graphene oxide nanosheets (functionalized graphene sheets). Graphene oxide is generally synthesized in aqueous solutions, and "dry" graphene oxide films contain a substantial amount of added water that collects between the oxygen-functionalized nanosheets.

Gupta and his team demonstrated a simple solvent drying technique to remove water within the sheets, which led to significant changes in their physical structure. Removing the water decreases the distance between the graphitic sheets. Gupta and his team observed the changes in the concentration of functional groups and the emergence of highly ordered structures.

These changes resulted in dramatically enhanced electrocatalytic activity, which significantly boosts the performance in fuel cells and batteries.


Story Source:

The above post is reprinted from materials provided by Los Alamos National Laboratory. Note: Content may be edited for style and length.


Journal Reference:

  1. U. Martinez, J. H. Dumont, E. F. Holby, K. Artyushkova, G. M. Purdy, A. Singh, N. H. Mack, P. Atanassov, D. A. Cullen, K. L. More, M. Chhowalla, P. Zelenay, A. M. Dattelbaum, A. D. Mohite, G. Gupta. Critical role of intercalated water for electrocatalytically active nitrogen-doped graphitic systems. Science Advances, 2016; 2 (3): e1501178 DOI: 10.1126/sciadv.1501178

Cite This Page:

Los Alamos National Laboratory. "Novel water-removal technique boosts performance of carbon nanomaterials." ScienceDaily. ScienceDaily, 23 March 2016. <www.sciencedaily.com/releases/2016/03/160323152504.htm>.
Los Alamos National Laboratory. (2016, March 23). Novel water-removal technique boosts performance of carbon nanomaterials. ScienceDaily. Retrieved August 27, 2016 from www.sciencedaily.com/releases/2016/03/160323152504.htm
Los Alamos National Laboratory. "Novel water-removal technique boosts performance of carbon nanomaterials." ScienceDaily. www.sciencedaily.com/releases/2016/03/160323152504.htm (accessed August 27, 2016).