Oct. 18, 2011 The latest development by engineers of KIT is inspired by nature. To fill the porous electrodes of lithium-ion batteries more rapidly with liquid electrolyte, they use a physicochemical effect that also provides water transport in trees. The new process increases the throughput of battery production and reduces investment costs. This and other innovations will be presented by KIT at the eCarTec International Electromobility Fair in Munich from October 18 to 20.
The electrodes inside modern batteries are as porous as a sponge. Unlike household sponges, however, pore size is in the micrometer range. As a result, the electrode has a very large surface area and provides lots of space for the chemical processes during electric charge and discharge. This is necessary for developing batteries for electric vehicles that can cover large distances and be recharged rapidly. "But the pores have to be filled completely with the electrolyte for optimized operation," explains Dr. Wilhelm Pfleging from KIT. The liquid electrolyte is the transport medium, in which the charged ions can diffuse between anode and cathode in the battery. "Without electrolyte, there is no charge equalization inside and no electric current flow outside." The materials used in conventional high-energy batteries for automotive industry, however, show poor wetting of the electrode surface by the liquid electrolyte.
Consequently, much time and expenditure in battery production have been spent so far for making the electrolyte move into the smallest pore, if possible, and for maximizing battery performance. The liquid is forced to enter the material by expensive and time-consuming vacuum or storage processes at elevated temperatures. "Our new process allows reduction of this time span from several hours down to a few minutes," confirms Pfleging. To achieve this amazing effect, he relies on nature. By a mechanico-chemical technology, the electrodes are modified such that the electrolyte is sucked into the battery as water is sucked into high trees. As a result, the electrolyte spreads very rapidly over the complete material and performance data of batteries based on this principle are much better.
"This novel electrode modification drastically reduces the technical expenditure and production times needed for filling lithium-ion cells with electrolyte," acknowledges Andreas Gutsch. Under the Competence E project, he coordinates the activities of more than 250 scientists at KIT to utilize the large innovation potential of a number of partial improvements and to further develop the entire system.
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