Featured Research

from universities, journals, and other organizations

New kid on the plasmonic block: Researchers find plasmonic resonances in semiconductor nanocrystals

Date:
April 20, 2011
Source:
DOE/Lawrence Berkeley National Laboratory
Summary:
Researchers have achieved plasmonic properties in the semiconductor nanocrystals known as quantum dots. Until now, plasmonic properties, which hold promise for superfast computers and ultrapowerful optical microscopes among many other possibilities, have been limited to nanostructures featuring interfaces between noble metals and dielectrics. This new discovery should make the already hot field of plasmonic technology even hotter.

Transmission electron micrographs and (inset) showing the electron diffraction patterns of three quantum dot samples with average size of (a) 2.4 nanometers (b) 3.6 nm, and (c) 5.8 nm.
Credit: Image courtesy of Alivisatos group

With its promise of superfast computers and ultrapowerful optical microscopes among the many possibilities, plasmonics has become one of the hottest fields in high-technology. However, to date plasmonic properties have been limited to nanostructures that feature interfaces between noble metals and dielectrics. Now, researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) have shown that plasmonic properties can also be achieved in the semiconductor nanocrystals known as quantum dots. This discovery should make the field of plasmonics even hotter.

"We have demonstrated well-defined localized surface plasmon resonances arising from p-type carriers in vacancy-doped semiconductor quantum dots that should allow for plasmonic sensing and manipulation of solid-state processes in single nanocrystals," says Berkeley Lab director Paul Alivisatos, a nanochemistry authority who led this research. "Our doped semiconductor quantum dots also open up the possibility of strongly coupling photonic and electronic properties, with implications for light harvesting, nonlinear optics, and quantum information processing."

Alivisatos is the corresponding author of a paper in the journal Nature Materials titled "Localized surface plasmon resonances arising from free carriers in doped quantum dots." Co-authoring the paper were Joseph Luther and Prashant Jain, along with Trevor Ewers.

The term "plasmonics" describes a phenomenon in which the confinement of light in dimensions smaller than the wavelength of photons in free space make it possible to match the different length-scales associated with photonics and electronics in a single nanoscale device. Scientists believe that through plasmonics it should be possible to design computer chip interconnects that are able to move much larger amounts of data much faster than today's chips. It should also be possible to create microscope lenses that can resolve nanoscale objects with visible light, a new generation of highly efficient light-emitting diodes, and supersensitive chemical and biological detectors. There is even evidence that plasmonic materials can be used to bend light around an object, thereby rendering that object invisible.

The plasmonic phenomenon was discovered in nanostructures at the interfaces between a noble metal, such as gold or silver, and a dielectric, such as air or glass. Directing an electromagnetic field at such an interface generates electronic surface waves that roll through the conduction electrons on a metal, like ripples spreading across the surface of a pond that has been plunked with a stone. Just as the energy in an electromagnetic field is carried in a quantized particle-like unit called a photon, the energy in such an electronic surface wave is carried in a quantized particle-like unit called a plasmon. The key to plasmonic properties is when the oscillation frequency between the plasmons and the incident photons matches, a phenomenon known as localized surface plasmon resonance (LSPR). Conventional scientific wisdom has held that LSPRs require a metal nanostructure , where the conduction electrons are not strongly attached to individual atoms or molecules. This has proved not to be the case as Prashant Jain, a member of the Alivisatos research group and one of the lead authors of the Nature Materials paper, explains.

"Our study represents a paradigm shift from metal nanoplasmonics as we've shown that, in principle, any nanostructure can exhibit LSPRs so long as the interface has an appreciable number of free charge carriers, either electrons or holes," Jain says. "By demonstrating LSPRs in doped quantum dots, we've extended the range of candidate materials for plasmonics to include semiconductors, and we've also merged the field of plasmonic nanostructures, which exhibit tunable photonic properties, with the field of quantum dots, which exhibit tunable electronic properties."

Jain and his co-authors made their quantum dots from the semiconductor copper sulfide, a material that is known to support numerous copper-deficient stoichiometries. Initially, the copper sulfide nanocrystals were synthesized using a common hot injection method. While this yielded nanocrystals that were intrinsically self-doped with p-type charge carriers, there was no control over the amount of charge vacancies or carriers.

"We were able to overcome this limitation by using a room-temperature ion exchange method to synthesize the copper sulfide nanocrystals," Jain says. "This freezes the nanocrystals into a relatively vacancy-free state, which we can then dope in a controlled manner using common chemical oxidants."

By introducing enough free electrical charge carriers via dopants and vacancies, Jain and his colleagues were able to achieve LSPRs in the near-infrared range of the electromagnetic spectrum. The extension of plasmonics to include semiconductors as well as metals offers a number of significant advantages, as Jain explains.

"Unlike a metal, the concentration of free charge carriers in a semiconductor can be actively controlled by doping, temperature, and/or phase transitions," he says. "Therefore, the frequency and intensity of LSPRs in dopable quantum dots can be dynamically tuned. The LSPRs of a metal, on the other hand, once engineered through a choice of nanostructure parameters, such as shape and size, is permanently locked-in."

Jain envisions quantum dots as being integrated into a variety of future film and chip-based photonic devices that can be actively switched or controlled, and also being applied to such optical applications as in vivo imaging. In addition, the strong coupling that is possible between photonic and electronic modes in such doped quantum dots holds exciting potential for applications in solar photovoltaics and artificial photosynthesis

"In photovoltaic and artificial photosynthetic systems, light needs to be absorbed and channeled to generate energetic electrons and holes, which can then be used to make electricity or fuel," Jain says. "To be efficient, it is highly desirable that such systems exhibit an enhanced interaction of light with excitons. This is what a doped quantum dot with an LSPR mode could achieve."

The potential for strongly coupled electronic and photonic modes in doped quantum dots arises from the fact that semiconductor quantum dots allow for quantized electronic excitations (excitons), while LSPRs serve to strongly localize or confine light of specific frequencies within the quantum dot. The result is an enhanced exciton-light interaction. Since the LSPR frequency can be controlled by changing the doping level, and excitons can be tuned by quantum confinement, it should be possible to engineer doped quantum dots for harvesting the richest frequencies of light in the solar spectrum.

Quantum dot plasmonics also hold intriguing possibilities for future quantum communication and computation devices.

"The use of single photons, in the form of quantized plasmons, would allow quantum systems to send information at nearly the speed of light, compared with the electron speed and resistance in classical systems," Jain says. "Doped quantum dots by providing strongly coupled quantized excitons and LSPRs and within the same nanostructure could serve as a source of single plasmons."

Jain and others in Alivsatos' research group are now investigating the potential of doped quantum dots made from other semiconductors, such as copper selenide and germanium telluride, which also display tunable plasmonic or photonic resonances. Germanium telluride is of particular interest because it has phase change properties that are useful for memory storage devices.

"A long term goal is to generalize plasmonic phenomena to all doped quantum dots, whether heavily self-doped or extrinsically doped with relatively few impurities or vacancies," Jain says.

This research was supported by the DOE Office of Science.


Story Source:

The above story is based on materials provided by DOE/Lawrence Berkeley National Laboratory. Note: Materials may be edited for content and length.


Journal Reference:

  1. Joseph M. Luther, Prashant K. Jain, Trevor Ewers, A. Paul Alivisatos. Localized surface plasmon resonances arising from free carriers in doped quantum dots. Nature Materials, 2011; DOI: 10.1038/nmat3004

Cite This Page:

DOE/Lawrence Berkeley National Laboratory. "New kid on the plasmonic block: Researchers find plasmonic resonances in semiconductor nanocrystals." ScienceDaily. ScienceDaily, 20 April 2011. <www.sciencedaily.com/releases/2011/04/110418135533.htm>.
DOE/Lawrence Berkeley National Laboratory. (2011, April 20). New kid on the plasmonic block: Researchers find plasmonic resonances in semiconductor nanocrystals. ScienceDaily. Retrieved April 19, 2014 from www.sciencedaily.com/releases/2011/04/110418135533.htm
DOE/Lawrence Berkeley National Laboratory. "New kid on the plasmonic block: Researchers find plasmonic resonances in semiconductor nanocrystals." ScienceDaily. www.sciencedaily.com/releases/2011/04/110418135533.htm (accessed April 19, 2014).

Share This



More Matter & Energy News

Saturday, April 19, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Small Reactors Could Be Future of Nuclear Energy

Small Reactors Could Be Future of Nuclear Energy

AP (Apr. 17, 2014) After the Fukushima nuclear disaster, the industry fell under intense scrutiny. Now, small underground nuclear power plants are being considered as the possible future of the nuclear energy. (April 17) Video provided by AP
Powered by NewsLook.com
Horseless Carriage Introduced at NY Auto Show

Horseless Carriage Introduced at NY Auto Show

AP (Apr. 17, 2014) An electric car that proponents hope will replace horse-drawn carriages in New York City has also been revealed at the auto show. (Apr. 17) Video provided by AP
Powered by NewsLook.com
Honda's New ASIMO Robot, More Human-Like Than Ever

Honda's New ASIMO Robot, More Human-Like Than Ever

AFP (Apr. 17, 2014) It walks and runs, even up and down stairs. It can open a bottle and serve a drink, and politely tries to shake hands with a stranger. Meet the latest ASIMO, Honda's humanoid robot. Duration: 00:54 Video provided by AFP
Powered by NewsLook.com
German Researchers Crack Samsung's Fingerprint Scanner

German Researchers Crack Samsung's Fingerprint Scanner

Newsy (Apr. 16, 2014) German researchers have used a fake fingerprint made from glue to bypass the fingerprint security system on Samsung's new Galaxy S5 smartphone. Video provided by Newsy
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:
from the past week

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins