Featured Research

from universities, journals, and other organizations

Crime Scene Investigations: Gunshot Residue Analysis On A Single Gunpowder Particle

Date:
April 9, 2008
Source:
American Chemical Society
Summary:
Scientists in Texas report development of a highly dependable, rapid and inexpensive new method for identifying the presence of gunshot residue. The test fills a detection gap that results from wider use of "green" -- lead free -- ammunition.

With what could be a shot in the arm for crime scene investigators, chemists have developed a reliable new test for detecting the presence of gun shot residue. Above is a residue particle -- roughly 1/20 the size of a period -- that has been magnified 200 times with a digital microscope.
Credit: Courtesy of Garrett Burleson

Scientists in Texas are reporting development of an highly dependable, rapid, and inexpensive new method for identifying the presence of gunshot residue (GSR). The test fills a GSR-detection gap that results from wider use of "green" -- lead free -- ammunition.

It requires only a single speck of GSR smaller than the period at the end of this sentence and could boost the accuracy of one of the most widely used tests employed at crime scenes involving gunplay.

In a poster presented at the 235th national meeting of the American Chemical Society, graduate student Garrett Lee Burleson and his advisor, chemist Jorn Chi Chung Yu, Ph.D., of Sam Houston State University in Huntsville, described their new method. It extracts almost all components of gunpowder residue from particles about 15 times smaller than the width of a human hair, without the use of chemical reagents. After extraction, gas chromatography coupled with a nitrogen phosphorus detector is used to separate and identify the analytes.

"Gunshot residue tests are done in almost every case where a shooting has taken place," Burleson said. "The main focus of our research is to develop a method that will help credibility of gunshot residue evidence in court. You can get results with this test in 30 to 40 minutes with the new test. In addition you only need small amounts of evidence to run the test."

Many of the current methods are susceptible to outside interferences that can produce false positive or false negative results. For example, most tests require the presence of lead for a valid reading, including two of the three mainstays of residue analysis -- the sodium rhodizonate test and scanning electron microscopy with energy dispersive x-ray detection.

But Burleson points out that lead is disappearing from ammunition. That potentially toxic metal poses environmental hazards at outdoor firing ranges, where it can leach into groundwater. In response, manufacturers have begun to create safer, environmentally friendly ammunition out of other metals, such as zinc and aluminum alloys.

This recent trend toward lead-free ammunition, Burleson said, has decreased reliability of gun shot residue analysis and created the need for smarter tests to identify more diverse components of residue in gunpowder, including elements like stabilizers and plasticizers, which are added in the powder during the manufacturing process for safety reasons.

"When a gun fires, the gunpowder explodes, producing gases at enormous pressure that propels the bullet out of the barrel of the firearm," explained Burleson, a graduate student in the Master of Science in Forensic Science Program at Sam Houston State University. "Some of the residue from that explosion is deposited on the hands of the shooter and the clothing of the victim." Burleson's new test, which uses a technology called solid phase micro-extraction combined with gas chromatography, focuses on chemical compounds present in that ejected material. "When you have a residue particle, no matter how small, it's going to contain signatures of every element in that powder."

These signatures offer a wider range of detection possibilities compared to traditional methods, he said. Using an alternative method with a scanning electron microscope, for example, a forensic examiner would perform a search for lead, passing up numerous powder constituents in the analysis. "You would just look for the one little piece of metal that might be there, so the analysis could take hours," Burleson said.

"If you're looking for powder, however, there's a lot more of it. You're getting more of the residue to analyze. It makes it a much more efficient method of detection." For example, a distinctive combination of certain chemicals, such as diphenylamine, ethyl centralite and nitrodiphenylamine, is typically found only in explosive mixtures and therefore allows for a simple analysis of gunplay at a crime scene.

In contrast, another traditional test for finding gunshot residue, the modified Griess test, often fails because it lacks such specificity. Its analysis is based on the detection of Nitrogen-based compounds called nitrites, which are gunpowder byproducts. But these compounds are also found elsewhere, leading to possible ambiguity in testing.

"Many chemical cleaners -- anything that can be used to take off motor oil or freight dust -- will test positive for gunshot residue using the Griess test," Burleson said.

That would make the reading a false positive, which opens the door in court cases for reasonable doubt and possibly incarcerating an innocent person. "The worst thing you can possibly say is, 'There's a chance I'm wrong.' Our preliminary results indicate you can determine the presence of gunshot residue with a high level of confidence."

More efficient testing also would reduce the need for extraneous tests that require time and money while draining resources from a criminal justice system that cannot afford it, Burleson said.

The research was funded by the College of Criminal Justice and Department of Chemistry at Sam Houston State University.

Burleson's test could be used as a preliminary or confirmatory one. "As far as a stand-alone test, it's an excellent, reliable and cheap test to do," he said. "But for the sake of clarity and thoroughness, examiners will usually run multiple tests, such as the sodium rhodizonate test at the crime scene, and they could then confirm the findings with my method."


Story Source:

The above story is based on materials provided by American Chemical Society. Note: Materials may be edited for content and length.


Cite This Page:

American Chemical Society. "Crime Scene Investigations: Gunshot Residue Analysis On A Single Gunpowder Particle." ScienceDaily. ScienceDaily, 9 April 2008. <www.sciencedaily.com/releases/2008/04/080407074558.htm>.
American Chemical Society. (2008, April 9). Crime Scene Investigations: Gunshot Residue Analysis On A Single Gunpowder Particle. ScienceDaily. Retrieved August 30, 2014 from www.sciencedaily.com/releases/2008/04/080407074558.htm
American Chemical Society. "Crime Scene Investigations: Gunshot Residue Analysis On A Single Gunpowder Particle." ScienceDaily. www.sciencedaily.com/releases/2008/04/080407074558.htm (accessed August 30, 2014).

Share This




More Matter & Energy News

Saturday, August 30, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Australian Airlines Relax Phone Ban Too

Australian Airlines Relax Phone Ban Too

Reuters - Business Video Online (Aug. 26, 2014) Qantas and Virgin say passengers can use their smartphones and tablets throughout flights after a regulator relaxed a ban on electronic devices during take-off and landing. As Hayley Platt reports the move comes as the two domestic rivals are expected to post annual net losses later this week. Video provided by Reuters
Powered by NewsLook.com
Hurricane Marie Brings Big Waves to California Coast

Hurricane Marie Brings Big Waves to California Coast

Reuters - US Online Video (Aug. 26, 2014) Huge waves generated by Hurricane Marie hit the Southern California coast. Rough Cut (no reporter narration). Video provided by Reuters
Powered by NewsLook.com
Chinese Researchers Might Be Creating Supersonic Submarine

Chinese Researchers Might Be Creating Supersonic Submarine

Newsy (Aug. 26, 2014) Chinese researchers have expanded on Cold War-era tech and are closer to building a submarine that could reach the speed of sound. Video provided by Newsy
Powered by NewsLook.com
Breakingviews: India Coal Strained by Supreme Court Ruling

Breakingviews: India Coal Strained by Supreme Court Ruling

Reuters - Business Video Online (Aug. 26, 2014) An acute coal shortage is likely to be aggravated as India's supreme court declared government coal allocations illegal, says Breakingviews' Peter Thal Larsen. Video provided by Reuters
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:
from the past week

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins