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Clues for superconductivity in an iron-based material

Date:
May 5, 2014
Source:
DOE/Oak Ridge National Laboratory
Summary:
For the first time, scientists have a clearer understanding of how to control the appearance of a superconducting phase in a material, adding crucial fundamental knowledge and perhaps setting the stage for advances in the field of superconductivity.

A change of Hall and Seebeck effects point to large Fermi surface modification at the structural transition, preventing superconductivity at low temperatures. The change in the Fermi surface topology has been confirmed by angle-resolved photoemission spectroscopy.
Credit: Image courtesy of DOE/Oak Ridge National Laboratory

For the first time, scientists have a clearer understanding of how to control the appearance of a superconducting phase in a material, adding crucial fundamental knowledge and perhaps setting the stage for advances in the field of superconductivity.

The paper, published in Physical Review Letters, focuses on a calcium-iron-arsenide single crystal, which has structural, thermodynamic and transport properties that can be varied through carefully controlled synthesis, similar to the application of pressure. To make this discovery, researchers focused on how these changes alter the material's Fermi surface, which maps the specific population and arrangement of electrons in materials.

"The Fermi surface is basically the 'genetic code' for causing a certain property, including superconductivity, in a material," said Athena Safa-Sefat of the Department of Energy's Oak Ridge National Laboratory, which led the research team. "We can make different phases of this material in single crystal forms and measure their structure and properties, but now we have Fermi surface signatures that explain why we can't induce superconductivity in a certain structural phase of this material."

Superconducting wires conduct electricity without resistance and could save the nation billions of dollars per year by virtually eliminating transmission losses on the grid, or they can be used to make compact, light and powerful motors and generators. This particular material is of special interest because it adds critical knowledge to the field of superconductivity that will ultimately allow such widespread applications.

The lead author of this paper, Krzysztof Gofryk, who did this work as a post-doctoral fellow at ORNL, showed how the interplay of structure and magnetism affected the Fermi surface and hence the electronic properties.

In calcium-iron-arsenide, the bulk superconducting state is absent because of the large Fermi surface modification at the structural transition.

This work represents a significant step forward for understanding this material's rich phase diagram and causes of superconductivity, Sefat said.

This research was funded by DOE's Office of Science and by LANL's Laboratory Directed Research and Development program.


Story Source:

The above story is based on materials provided by DOE/Oak Ridge National Laboratory. Note: Materials may be edited for content and length.


Journal Reference:

  1. K. Gofryk, B. Saparov, T. Durakiewicz, A. Chikina, S. Danzenbächer, D. V. Vyalikh, M. J. Graf, A. S. Sefat. Fermi-Surface Reconstruction and Complex Phase Equilibria in CaFe2As2. Phys. Rev. Lett., 2014 [link]

Cite This Page:

DOE/Oak Ridge National Laboratory. "Clues for superconductivity in an iron-based material." ScienceDaily. ScienceDaily, 5 May 2014. <www.sciencedaily.com/releases/2014/05/140505112621.htm>.
DOE/Oak Ridge National Laboratory. (2014, May 5). Clues for superconductivity in an iron-based material. ScienceDaily. Retrieved October 23, 2014 from www.sciencedaily.com/releases/2014/05/140505112621.htm
DOE/Oak Ridge National Laboratory. "Clues for superconductivity in an iron-based material." ScienceDaily. www.sciencedaily.com/releases/2014/05/140505112621.htm (accessed October 23, 2014).

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