ScienceDaily (Nov. 29, 2004) — It's the scientific equivalent of having your cake and eating it too. A team of researchers from JILA, a joint institute of the Commerce Department's National Institute of Standards and Technology and the University of Colorado at Boulder, has developed an efficient, low-cost way to measure the energy levels of atoms in a gas with extremely high accuracy, and simultaneously detect and control transitions between the levels as fast as they occur. The technique is expected to have practical applications in many fields including astrophysics, quantum computing, chemical analysis, and chemical synthesis.

Described in the Nov. 18 online issue of Science Express,* the method uses ultrafast pulses of laser light like a high speed movie camera to record in real-time the energy required to boost an atom's outer electrons from one orbital pattern to another. The pulses are so short that scientists can track precisely the fraction of atoms in each energy state and how those populations change with time. Moreover, the atoms respond to subsequent laser pulses cumulatively--the energy adds up over time--which allows fine-tuning to affect specific orbital patterns of interest with a much lower power laser than usual.

All of chemistry depends on the configurations of these outer electrons. The technique promises to make it easier for scientists to systematically understand the radiation "signatures" (or spectra) given off by atoms and molecules as their electrons jump between different energy levels. Ultimately, it should allow improved control of the complex chain of events that combines atoms into desired compounds.

The JILA team is a world leader in applying so-called "frequency combs" to practical science problems. The laser system used in the current work emits a hundred thousand different infrared frequencies at once in individual pulses lasting just femtoseconds (quadrillionths of a second). The JILA researchers used the laser to precisely study the electron energy levels within an ultracold gas of rubidium atoms. The ability to probe atoms with many different laser frequencies simultaneously and to monitor atom responses in real time should allow scientists to study and control systems in a vastly more efficient and precise manner.

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* A. Marian, M. C. Stowe, J. R. Lawall, D. Felinto, and J. Ye. 2004. "United time-frequency spectroscopy for dynamics and global structure." Science Express. Nov. 18.

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Adapted from materials provided by National Institute Of Standards And Technology.

Just as a satellite requires a boost of power to change from one Earth orbit to a higher one, electrons require an energy boost (in quantum steps) to change from one orbital pattern around the nucleus to another. JILA researchers used pulses of ultrafast laser light to boost the outer electron in rubidum atoms to higher, "excited" levels, then detected the energy released by the atoms in the form of fluorescent light as they "relaxed" back to their natural state. This three-dimensional plot shows changes in the intensity of the light emitted by the atoms in 300 microseconds. The JILA technique should allow scientists to measure and control these "transitions" between atomic energy levels much more efficiently than with conventional methods. (Graphic courtesy of National Institute Of Standards And Technology)

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