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How Crystal Becomes A Conductor

Date:
February 6, 2008
Source:
University of California - Davis
Summary:
Squeeze a crystal of manganese oxide hard enough, and it changes from an electrical insulator to a conductive metal. Researchers use computational modeling to show why this happens. The results represent an advance in computer modeling of these materials and could shed light on the behavior of similar minerals deep in the Earth.

Squeeze a crystal of manganese oxide hard enough, and it changes from an electrical insulator to a conductive metal. In a new report researchers use computational modeling to show why this happens.

The results represent an advance in computer modeling of these materials and could shed light on the behavior of similar minerals deep in the Earth, said Warren Pickett, professor of physics at UC Davis and an author on the study.

Manganese oxide is magnetic but does not conduct electricity under normal conditions because of strong interactions between the electrons surrounding atoms in the crystal, Pickett said. But under pressures of about a million atmospheres (one megabar), manganese oxide transitions to a metallic state.

Pickett and colleagues Richard Scalettar at UC Davis, Jan Kunes at the University of Augsburg, Germany, Alexey Lukoyanov at the Ural State Technical University, Russia, and Vladimir Anisimov at the Institute of Metal Physics in Yekaterinburg, Russia, built and ran computational models of manganese oxide.

Using the model, the researchers were able to test different explanations for the transition and identify the microscopic mechanism responsible. They found that when the atoms are forced together under high pressure, the magnetic properties of the manganese atoms become unstable and collapse, freeing the electrons to move through the crystal.

Manganese oxide has similar properties to iron oxide and silicates (silicon oxides), which make up a major part of the Earth's crust and mantle. Understanding how these materials behave under enormous pressures deep underground could help geologists understand the Earth's interior, Pickett said.

The paper was published Feb. 3 in the online edition of the journal Nature Materials.


Story Source:

The above story is based on materials provided by University of California - Davis. Note: Materials may be edited for content and length.


Cite This Page:

University of California - Davis. "How Crystal Becomes A Conductor." ScienceDaily. ScienceDaily, 6 February 2008. <www.sciencedaily.com/releases/2008/02/080205170602.htm>.
University of California - Davis. (2008, February 6). How Crystal Becomes A Conductor. ScienceDaily. Retrieved July 29, 2014 from www.sciencedaily.com/releases/2008/02/080205170602.htm
University of California - Davis. "How Crystal Becomes A Conductor." ScienceDaily. www.sciencedaily.com/releases/2008/02/080205170602.htm (accessed July 29, 2014).

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