Featured Research

from universities, journals, and other organizations

Purer Water With Long Shelf Life Made Possible With One Atom Change To Water Purification Product

Date:
July 23, 2009
Source:
DOE/Sandia National Laboratories
Summary:
By substituting a single atom in a molecule widely used to purify water, researchers have created a far more effective decontaminant with a shelf life superior to products currently on the market. The substitution isn’t performed atom by atom using nanoscopic tweezers but rather uses a simple chemical process of dissolving aluminum salts in water, gallium salts into a sodium hydroxide solution and then slowly adding the sodium hydroxide solution to the aluminum solution while heating.

This bar graph shows the efficacy of removing wild-type bacteriophage from Rio Grande water using the all-aluminum coagulant (yellow), the gallium-aluminum coagulant (pink) and a germanium-aluminum coagulant (green). While the gallium-aluminum coagulant is most effective, the germanium-aluminum coagulant is less effective than the all-aluminum coagulant. The gallium makes the active ingredient for binding contaminants more stable and effective, while the germanium, introduced as another variable, was found to make the active ingredient less stable and less effective.
Credit: Image courtesy of DOE/Sandia National Laboratories

By substituting a single atom in a molecule widely used to purify water, researchers at Sandia National Laboratories have created a far more effective decontaminant with a shelf life superior to products currently on the market.

Sandia has applied for a patent on the material, which removes bacterial, viral and other organic and inorganic contaminants from river water destined for human consumption, and from wastewater treatment plants prior to returning water to the environment.

“Human consumption of ‘challenged’ water is increasing worldwide as preferred supplies become more scarce,” said Sandia principal investigator May Nyman. “Technological advances like this may help solve problems faced by water treatment facilities in both developed and developing countries.”

The study was published in June 2009 in the journal Environmental Science & Technology (a publication of the American Chemical Society) and highlighted in the June 22 edition of Chemical & Engineering News. Sandia is working with a major producer of water treatment chemicals to explore the commercial potential of the compound.

The water-treatment reagent, known as a coagulant, is made by substituting an atom of gallium in the center of an aluminum oxide cluster — itself a commonly used coagulant in water purification, says Nyman.

The substitution isn’t performed atom by atom using nanoscopic tweezers but rather uses a simple chemical process of dissolving aluminum salts in water, gallium salts into a sodium hydroxide solution and then slowly adding the sodium hydroxide solution to the aluminum solution while heating.

“The substitution of a single gallium atom in that compound makes a big difference,” said Nyman. “It greatly improves the stability and effectiveness of the reagent. We’ve done side-by-side tests with a variety of commercially available products. For almost every case, ours performs best under a wide range of conditions.”

Wide-ranging conditions are inevitable, she said, when dealing with a natural water source such as a river. “You get seasonal and even daily fluctuations in pH, temperature, turbidity and water chemistry. And a river in central New Mexico has very different conditions than say, a river in Ohio.”

The Sandia coagulant attracts and binds contaminants so well because it maintains its electrostatic charge more reliably than conventional coagulants made without gallium, itself a harmless addition.

The new material also resists converting to larger, less-reactive aggregates before it is used. This means it maintains a longer shelf life, avoiding the problem faced by related commercially available products that aggregate over time.

“The chemical substitution [of a gallium atom for an aluminum atom] has been studied by Sandia’s collaborators at the University of California at Davis, but nobody has ever put this knowledge to use in an application such as removing water contaminants like microorganisms,” said Nyman.

The project was conceived and all water treatment studies were performed at Sandia, said Nyman, who worked with Sandia microbiologist Tom Stewart. Transmission electron microscope images of bacteriophages binding to the altered material were achieved at the University of New Mexico. Mass spectroscopy of the alumina clusters in solution was performed at UC Davis.

The work was sponsored by Sandia’s Laboratory Directed Research Development office.


Story Source:

The above story is based on materials provided by DOE/Sandia National Laboratories. Note: Materials may be edited for content and length.


Cite This Page:

DOE/Sandia National Laboratories. "Purer Water With Long Shelf Life Made Possible With One Atom Change To Water Purification Product." ScienceDaily. ScienceDaily, 23 July 2009. <www.sciencedaily.com/releases/2009/07/090721144643.htm>.
DOE/Sandia National Laboratories. (2009, July 23). Purer Water With Long Shelf Life Made Possible With One Atom Change To Water Purification Product. ScienceDaily. Retrieved July 23, 2014 from www.sciencedaily.com/releases/2009/07/090721144643.htm
DOE/Sandia National Laboratories. "Purer Water With Long Shelf Life Made Possible With One Atom Change To Water Purification Product." ScienceDaily. www.sciencedaily.com/releases/2009/07/090721144643.htm (accessed July 23, 2014).

Share This




More Matter & Energy News

Wednesday, July 23, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Government Approves East Coast Oil Exploration

Government Approves East Coast Oil Exploration

AP (July 18, 2014) The Obama administration approved the use of sonic cannons to discover deposits under the ocean floor by shooting sound waves 100 times louder than a jet engine through waters shared by endangered whales and turtles. (July 18) Video provided by AP
Powered by NewsLook.com
Sunken German U-Boat Clearly Visible For First Time

Sunken German U-Boat Clearly Visible For First Time

Newsy (July 18, 2014) The wreckage of the German submarine U-166 has become clearly visible for the first time since it was discovered in 2001. Video provided by Newsy
Powered by NewsLook.com
Obama: U.S. Must Have "smartest Airports, Best Power Grid"

Obama: U.S. Must Have "smartest Airports, Best Power Grid"

Reuters - US Online Video (July 17, 2014) President Barak Obama stopped by at a lunch counter in Delaware before making remarks about boosting the nation's infrastructure. Mana Rabiee reports. Video provided by Reuters
Powered by NewsLook.com
Crude Oil Prices Bounce Back After Falling Below $100 a Barrel

Crude Oil Prices Bounce Back After Falling Below $100 a Barrel

TheStreet (July 16, 2014) Oil Futures are bouncing back after tumbling below $100 a barrel for the first time since May yesterday. Jeff Grossman is the president of BRG Brokerage and trades at the NYMEX. Grossman tells TheStreet the Middle East is always a concern for oil traders. Oil prices were pushed down in recent weeks on Libya increasing its production. Supply disruptions in Iraq fading also contributed to prices falling. News from China's economic front showing a growth for the second quarter also calmed fears on its slowdown. Jeff Grossman talks to TheStreet's Susannah Lee on this and more on the Energy Department's Energy Information Administration (EIA) report. Video provided by TheStreet
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:
from the past week

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins