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Single-molecule devices can serve as powerful new science tools

Date:
June 11, 2010
Source:
Cornell University
Summary:
With controlled stretching of molecules, researchers have demonstrated that single-molecule devices can serve as powerful new tools for fundamental science experiments. Their work has resulted in detailed tests of long-existing theories on how electrons interact at the nanoscale.

A scanning electron micrograph of a gold bridge suspended 40 nanometers above a silicon substrate. In the experiment, the bridge is severed in the middle, a single molecule is suspended across the gap, and the substrate is bent to stretch the molecule while simultaneously measuring the electron current through the molecule.
Credit: J.J. Parks

With controlled stretching of molecules, Cornell researchers have demonstrated that single-molecule devices can serve as powerful new tools for fundamental science experiments. Their work has resulted in detailed tests of long-existing theories on how electrons interact at the nanoscale.

The work, led by professor of physics Dan Ralph, is published in the June 10 online edition of the journal Science. First author is J.J. Parks, a former graduate student in Ralph's lab.

The scientists studied particular cobalt-based molecules with so-called intrinsic spin -- a quantized amount of angular momentum.

Theories first postulated in the 1980s predicted that molecular spin would alter the interaction between electrons in the molecule and conduction electrons surrounding it, and that this interaction would determine how easily electrons flow through the molecule. Before now, these theories had not been tested in detail because of the difficulties involved in making devices with controlled spins.

Understanding single-molecule electronics requires expertise in both chemistry and physics, and Cornell's team has specialists in both.

"People know about high-spin molecules, but no one has been able to bring together the chemistry and physics to make controlled contact with these high-spin molecules," Ralph said.

The researchers made their observations by stretching individual spin-containing molecules between two electrodes and analyzing their electrical properties. They watched electrons flow through the cobalt complex, cooled to extremely low temperatures, while slowly pulling on the ends to stretch it. At a particular point, it became more difficult to pass current through the molecule. The researchers had subtly changed the magnetic properties of the molecule by making it less symmetric.

After releasing the tension, the molecule returned to its original shape and began passing current more easily -- thus showing the molecule had not been harmed. Measurements as a function of temperature, magnetic field and the extent of stretching gave the team new insights into exactly what is the influence of molecular spin on the electron interactions and electron flow.

The effects of high spin on the electrical properties of nanoscale devices were entirely theoretical issues before the Cornell work, Ralph said. By making devices containing individual high-spin molecules and using stretching to control the spin, the Cornell team proved that such devices can serve as a powerful laboratory for addressing these fundamental scientific questions.

The study was funded primarily by the National Science Foundation.


Story Source:

The above story is based on materials provided by Cornell University. The original article was written by Anne Ju. Note: Materials may be edited for content and length.


Journal Reference:

  1. J. J. Parks, A. R. Champagne, T. A. Costi, W. W. Shum, A. N. Pasupathy, E. Neuscamman, S. Flores-Torres, P. S. Cornaglia, A. A. Aligia, C. A. Balseiro, G. K.-L. Chan, H. D. Abruña, and D. C. Ralph. Mechanical Control of Spin States in Spin-1 Molecules and the Underscreened Kondo Effect. Science, June 10, 2010 DOI: 10.1126/science.1186874

Cite This Page:

Cornell University. "Single-molecule devices can serve as powerful new science tools." ScienceDaily. ScienceDaily, 11 June 2010. <www.sciencedaily.com/releases/2010/06/100610141040.htm>.
Cornell University. (2010, June 11). Single-molecule devices can serve as powerful new science tools. ScienceDaily. Retrieved July 23, 2014 from www.sciencedaily.com/releases/2010/06/100610141040.htm
Cornell University. "Single-molecule devices can serve as powerful new science tools." ScienceDaily. www.sciencedaily.com/releases/2010/06/100610141040.htm (accessed July 23, 2014).

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