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Gold nanoparticles create visible-light catalysis in nanowires

Date:
June 21, 2010
Source:
DOE/Argonne National Laboratory
Summary:
Scientists have created visible-light catalysis, using silver chloride nanowires decorated with gold nanoparticles, that may decompose organic molecules in polluted water.
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A scientist at the U.S. Department of Energy's (DOE) Argonne National Laboratory has created visible-light catalysis, using silver chloride nanowires decorated with gold nanoparticles, that may decompose organic molecules in polluted water.

"Silver nanowires have been extensively studied and used for a variety of applications, including transparent conductive electrodes for solar cells and optoelectronic devices," said nanoscientist Yugang Sun of Argonne's Center for Nanoscale Materials. "By chemically converting them into semiconducting silver chloride nanowires, followed by adding gold nanoparticles, we have created nanowires with a completely new set of properties that are significantly different from the original nanowires."

Traditional silver chloride photocatalytic properties are restricted to ultraviolet and blue light wavelengths, but with the addition of the gold nanoparticles, they become photocatalytic in visible light. The visible light excites the electrons in the gold nanoparticles and initiates reactions that culminate in charge separation on the silver chloride nanowires. Tests have already shown that gold-decorated nanowires can decompose organic molecules such as methylene blue.

"If you were to create a film of gold-decorated nanowires and allow polluted water to flow through it, the organic molecules may be destroyed with visible irradiation from conventional fluorescent light bulbs or the sun," Sun said.

Sun started with traditional silver nanowires that were oxidized with iron chloride to create silver chloride nanowires. A sequential reaction with sodium tetrachloroaurate deposited the gold nanoparticles on the wires.

Sun said it is possible to use a similar mechanism to deposit other metals such as palladium and platinum onto the silver chloride nanowires and create new properties, such as the ability to catalyze the splitting of water into hydrogen with sunlight.

A paper on this research was published in the Journal of Physical Chemistry C.

Funding was provided by the U.S. Department of Energy Office of Science. The Center for Nanoscale Materialsat Argonne National Laboratory is one of the five DOE Nanoscale Science Research Centers (NSRCs), premier national user facilities for interdisciplinary research at the nanoscale, supported by the DOE Office of Science.


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Materials provided by DOE/Argonne National Laboratory. Note: Content may be edited for style and length.


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DOE/Argonne National Laboratory. "Gold nanoparticles create visible-light catalysis in nanowires." ScienceDaily. ScienceDaily, 21 June 2010. <www.sciencedaily.com/releases/2010/06/100615122534.htm>.
DOE/Argonne National Laboratory. (2010, June 21). Gold nanoparticles create visible-light catalysis in nanowires. ScienceDaily. Retrieved March 28, 2024 from www.sciencedaily.com/releases/2010/06/100615122534.htm
DOE/Argonne National Laboratory. "Gold nanoparticles create visible-light catalysis in nanowires." ScienceDaily. www.sciencedaily.com/releases/2010/06/100615122534.htm (accessed March 28, 2024).

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