Featured Research

from universities, journals, and other organizations

Nanoparticles: Peering into the never-before-seen

Date:
June 17, 2010
Source:
DOE/Lawrence Livermore National Laboratory
Summary:
Scientists can now peer into the inner workings of catalyst nanoparticles 3,000 times smaller than a human hair within nanoseconds.

Making adjustments to the dynamic transmission electron microscope. From left: Curtis Brown, Thomas LaGrange and Judy Kim.
Credit: Image courtesy of DOE/Lawrence Livermore National Laboratory

Scientists can now peer into the inner workings of catalyst nanoparticles 3,000 times smaller than a human hair within nanoseconds.

Related Articles


The findings point the way toward future work that could greatly improve catalyst efficiency in a variety of processes that are crucial to the world's energy security, such as petroleum catalysis and catalyst-based nanomaterial growth for next-generation rechargeable batteries. The work was performed in a collaborative effort by Lawrence Livermore National Laboratory and the University of California at Davis.

Using a new imaging technique on Lawrence Livermore's Dynamic Transmission Electron Microscope (DTEM), researchers have achieved unprecedented spatial and temporal resolution in single-shot images of nanoparticulate catalysts.

The DTEM uses a laser-driven photocathode to produce short pulses of electrons capable of recording electron micrographs with 15-nanosecond (one billionth of a second) exposure time. The recent addition of an annular dark field (ADF) aperture to the instrument has greatly improved its ability to time-resolve images of nanoparticles as small as 30 nanometers in diameter.

"Nanoparticles in this size range are of crucial importance to a wide variety of catalytic process of keen interest to energy and nanotechnology researchers," said UC Davis' Dan Masiel, formerly of LLNL and lead author of a paper appearing in the journal, ChemPhysChem. "Time-resolved imaging of such materials will allow for unprecedented insight into the dynamics of their behavior."

Previously, particles smaller than 50 nanometers could not be resolved in the 15-nanosecond exposure because of the limited signal and low contrast without ADF aperature. But by using DTEM's ADF, almost every 50-nanometer particle and many 30-nanometer ones became clearly visible because of the fast time resolution and high contrast.

"The stark difference between these two images clearly demonstrates the efficacy of annual dark field imaging when imaging samples with feature sizes near the resolution limit of DTEM," Masiel said.

The new technique makes it easier to discern significant features when compared to bright field pulsed imaging. It allows for vastly improved contrast for smaller particles, widening the range of catalyst systems that can be studied using DTEM.

DTEM can record images with six orders of magnitude higher temporal resolution than conventional TEM and can provide important insights into processes such as phase transformations, chemical reactions and nanowire and nanotube growth.

Co-authors include LLNL's Bryan Reed, Thomas LaGrange, Geoffrey Campbell, Ting Guo and Nigel Browning. The work was funded by the Department of Energy's Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division.

The article appears in the May 27 online edition of ChemPhys Chem.


Story Source:

The above story is based on materials provided by DOE/Lawrence Livermore National Laboratory. Note: Materials may be edited for content and length.


Journal Reference:

  1. Daniel J. Masiel, Bryan W. Reed, Thomas B. LaGrange, Geoffrey H. Campbell, Ting Guo, Nigel D. Browning. Time-Resolved Annular Dark Field Imaging of Catalyst Nanoparticles. ChemPhysChem, 2010; DOI: 10.1002/cphc.201000274

Cite This Page:

DOE/Lawrence Livermore National Laboratory. "Nanoparticles: Peering into the never-before-seen." ScienceDaily. ScienceDaily, 17 June 2010. <www.sciencedaily.com/releases/2010/06/100616151635.htm>.
DOE/Lawrence Livermore National Laboratory. (2010, June 17). Nanoparticles: Peering into the never-before-seen. ScienceDaily. Retrieved October 24, 2014 from www.sciencedaily.com/releases/2010/06/100616151635.htm
DOE/Lawrence Livermore National Laboratory. "Nanoparticles: Peering into the never-before-seen." ScienceDaily. www.sciencedaily.com/releases/2010/06/100616151635.htm (accessed October 24, 2014).

Share This



More Matter & Energy News

Friday, October 24, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Police Testing New Gunfire Tracking Technology

Police Testing New Gunfire Tracking Technology

AP (Oct. 24, 2014) A California-based startup has designed new law enforcement technology that aims to automatically alert dispatch when an officer's gun is unholstered and fired. Two law enforcement agencies are currently testing the technology. (Oct. 24) Video provided by AP
Powered by NewsLook.com
3D Printed Instruments Make Sweet Music in Sweden

3D Printed Instruments Make Sweet Music in Sweden

Reuters - Innovations Video Online (Oct. 23, 2014) Students from Lund University's Malmo Academy of Music are believed to be the world's first band to all use 3D printed instruments. The guitar, bass guitar, keyboard and drums were built by Olaf Diegel, professor of product development, who says 3D printing allows musicians to design an instrument to their exact specifications. Matthew Stock reports. Video provided by Reuters
Powered by NewsLook.com
NYPD Gives High Tech Anti-Terror Weapon to 41,000 Officers

NYPD Gives High Tech Anti-Terror Weapon to 41,000 Officers

Buzz60 (Oct. 23, 2014) New York City officials announce a new technology initiative for the NYPD. Tim Minton reports smartphones and tablets will be given to more than 40,000 NYPD officers and detectives in an effort to change the way they perform their duties. Video provided by Buzz60
Powered by NewsLook.com
Chameleon Camouflage to Give Tanks Cloaking Capabilities

Chameleon Camouflage to Give Tanks Cloaking Capabilities

Reuters - Innovations Video Online (Oct. 22, 2014) Inspired by the way a chameleon changes its colour to disguise itself; scientists in Poland want to replace traditional camouflage paint with thousands of electrochromic plates that will continuously change colour to blend with its surroundings. The first PL-01 concept tank prototype will be tested within a few years, with scientists predicting that a similar technology could even be woven into the fabric of a soldiers' clothing making them virtually invisible to the naked eye. Matthew Stock reports. Video provided by Reuters
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:

Strange & Offbeat Stories


Space & Time

Matter & Energy

Computers & Math

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins