Featured Research

from universities, journals, and other organizations

Metallic alloy is tough and ductile at cryogenic temperatures

Date:
September 4, 2014
Source:
DOE/Lawrence Berkeley National Laboratory
Summary:
A multi-element high-entropy alloy not only tests out as one of the toughest materials on record, but, unlike most materials, the toughness as well as the strength and ductility of this alloy actually improves at cryogenic temperatures.

At 77K, back‐scattered electron images taken in the wake of a propagated crack show the formation of pronounced cell structures resulting from dislocation activity that includes deformation‐induced nano‐twinning.
Credit: Courtesy of Ritchie group

A new concept in metallic alloy design -- called "high‐entropy alloys" -- has yielded a multiple-element material that not only tests out as one of the toughest on record, but, unlike most materials, the toughness as well as the strength and ductility of this alloy actually improves at cryogenic temperatures. This multi-element alloy was synthesized and tested through a collaboration of researchers at the U.S. Department of Energy (DOE)'s Lawrence Berkeley and Oak Ridge National Laboratories (Berkeley Lab and ORNL).

"We examined CrMnFeCoNi, a high‐entropy alloy that contains five major elements rather than one dominant one," says Robert Ritchie, a materials scientist with Berkeley Lab's Materials Sciences Division. "Our tests showed that despite containing multiple elements with different crystal structures, this alloy crystalizes as a single phase, face‐centered cubic solid with exceptional damage tolerance, tensile strength above one gigapascal, and fracture toughness values that are off the charts, exceeding that of virtually all other metallic alloys."

Ritchie is the corresponding author along with ORNL's Easo George of a paper in Science describing this research. The paper is titled "A fracture resistant high‐entropy alloy for cryogenic applications." Co-authors are Bernd Gludovatz, Anton Hohenwarter, DhirajCatoor and Edwin Chang.

The tradition of mixing two metals together to create an alloy that possesses properties its constituent elements individually lack goes back thousands of years. In the 4th millennium BC, people began adding tin, a hard metal, to copper, a soft and relatively easy to work metal, to produce bronze, an alloy much stronger than copper. It was later discovered that adding carbon to iron yields the much stronger steel, and the addition of nickel and chromium to the mix yields steel that resists corrosion. Traditional alloys invariably feature a single dominant constituent with minor elements mixed in, and often rely on the presence of a second phase for mechanical performance.

"High‐entropy alloys represent a radical departure from tradition," Ritchie says, "in that they do not derive their properties from a single dominant constituent or from a second phase. The idea behind this concept is that configurational entropy increases with the number of alloying elements, counteracting the propensity for compound formation and stabilizing these alloys into a single phase like a pure metal."

Although high‐entropy alloys have been around for more than a decade, it has only been recently that the quality of these alloys has been sufficient for scientific study. George and his research group at ORNL combined high‐purity elemental starting materials with an arc-melting and drop-casting process to produce high quality samples of CrMnFeCoNi (chromium, manganese, iron, cobalt and nickel) in sheets roughly 10 millimeters thick. After characterizing these samples for tensile properties and microstructure, the ORNL team sent them to Ritchie and his research group for fracture and toughness characterization.

Ritchie, who holds the H. T. and Jessie Chua Distinguished Professor of Engineering chair at the University of California (UC) Berkeley, is an internationally recognized authority on the mechanical behavior of materials.

"As high entropy alloys are single phase, we reasoned that they would be ideal for cryogenic applications, such as storage tanks for liquefied natural gas, hydrogen and oxygen," he says. "Our work is the first in-depth study that characterizes the fracture toughness properties of this class of alloys, and lo and behold, they are spectacular!"

Tensile strengths and fracture toughness values were measured for CrMnFeCoNi from room temperature down to 77 Kelvin, the temperature of liquid nitrogen. The values recorded were among the highest reported for any material. That these values increased along with ductility at cryogenic temperatures is a huge departure from the vast majority of metallic alloys, which lose ductility and become more brittle at lower temperatures. Ritchie and George believe that the key to CrMnFeCoN's remarkable cryogenic strength, ductility and toughness is a phenomenon known as "nano-twinning," in which during deformation, the atomic arrangements in adjacent crystalline regions form mirror images of one another.

"These nano-twins are created when the material undergoes plastic deformation at cryogenic temperatures," Ritchie says. "This represents a mechanism of plasticity in addition to the planar-slip dislocation activity most metals undergo at ambient temperatures. The result of nano-twinning deformation is a continuous strain hardening, which acts to suppress the localized deformation that causes premature failure."

Ritchie notes that the mechanical properties of CrMnFeCoNi and other high-entropy alloys have yet to be optimized.

"These high-entropy alloys may well be capable of even better properties," he says.


Story Source:

The above story is based on materials provided by DOE/Lawrence Berkeley National Laboratory. Note: Materials may be edited for content and length.


Journal Reference:

  1. Bernd Gludovatz, Anton Hohenwarter, Dhiraj Catoor, Edwin H. Chang, Easo P. George, and Robert O. Ritchie. A fracture-resistant high-entropy alloy for cryogenic applications. Science, 5 September 2014: 1153-1158 DOI: 10.1126/science.1254581

Cite This Page:

DOE/Lawrence Berkeley National Laboratory. "Metallic alloy is tough and ductile at cryogenic temperatures." ScienceDaily. ScienceDaily, 4 September 2014. <www.sciencedaily.com/releases/2014/09/140904144648.htm>.
DOE/Lawrence Berkeley National Laboratory. (2014, September 4). Metallic alloy is tough and ductile at cryogenic temperatures. ScienceDaily. Retrieved October 21, 2014 from www.sciencedaily.com/releases/2014/09/140904144648.htm
DOE/Lawrence Berkeley National Laboratory. "Metallic alloy is tough and ductile at cryogenic temperatures." ScienceDaily. www.sciencedaily.com/releases/2014/09/140904144648.htm (accessed October 21, 2014).

Share This



More Matter & Energy News

Tuesday, October 21, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Gulfstream G500, G600 Unveiling

Gulfstream G500, G600 Unveiling

Flying (Oct. 20, 2014) Watch Gulfstream's public launch of the G500 and G600 at their headquarters in Savannah, Ga., along with a surprise unveiling of the G500, which taxied up under its own power. Video provided by Flying
Powered by NewsLook.com
Japanese Scientists Unveil Floating 3D Projection

Japanese Scientists Unveil Floating 3D Projection

Reuters - Innovations Video Online (Oct. 20, 2014) Scientists in Tokyo have demonstrated what they say is the world's first 3D projection that floats in mid air. A laser that fires a pulse up to a thousand times a second superheats molecules in the air, creating a spark which can be guided to certain points in the air to shape what the human eye perceives as an image. Matthew Stock reports. Video provided by Reuters
Powered by NewsLook.com
Hey, Doc! Sewage, Beer and Food Scraps Can Power Chevrolet’s Bi-Fuel Impala

Hey, Doc! Sewage, Beer and Food Scraps Can Power Chevrolet’s Bi-Fuel Impala

3BL Media (Oct. 20, 2014) Hey, Doc! Sewage, Beer and Food Scraps Can Power Chevrolet’s Bi-fuel Impala Video provided by 3BL
Powered by NewsLook.com
What We Know About Microsoft's Rumored Smartwatch

What We Know About Microsoft's Rumored Smartwatch

Newsy (Oct. 20, 2014) Microsoft will reportedly release a smartwatch that works across different mobile platforms, has a two-day battery life and tracks heart rate. Video provided by Newsy
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:

Strange & Offbeat Stories


Space & Time

Matter & Energy

Computers & Math

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins