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Scientists create 'molecular paper' -- largest two-dimensional polymer crystal self-assembled in water

Date:
April 15, 2010
Source:
DOE/Lawrence Berkeley National Laboratory
Summary:
Scientists have created "molecular paper," the largest two-dimensional polymer crystal self-assembled in water to date. This entirely new sheet material is made of peptoids, engineered polymers that can flex and fold like proteins while maintaining the robustness of synthetic materials.

Ron Zuckermann (left) and Ki Tae Nam with Berkeley Lab’s Molecular Foundry, have developed a ‘molecular paper’ material whose properties can be precisely tailored to control the flow of molecules, or serve as a platform for chemical and biological detection.
Credit: Photo by Roy Kaltschmidt, Berkeley Lab Public Affairs

Two-dimensional, "sheet-like" nanostructures are commonly employed in biological systems such as cell membranes, and their unique properties have inspired interest in materials such as graphene. Now, Berkeley Lab scientists have made the largest two-dimensional polymer crystal self-assembled in water to date. This entirely new material mirrors the structural complexity of biological systems with the durable architecture needed for membranes or integration into functional devices.

These self-assembling sheets are made of peptoids, engineered polymers that can flex and fold like proteins while maintaining the robustness of synthetic materials. Each sheet is just two molecules thick yet hundreds of square micrometers in area -- akin to 'molecular paper' large enough to be visible to the naked eye. What's more, unlike a typical polymer, each building block in a peptoid nanosheet is encoded with structural 'marching orders' -- suggesting its properties can be precisely tailored to an application. For example, these nanosheets could be used to control the flow of molecules, or serve as a platform for chemical and biological detection.

"Our findings bridge the gap between natural biopolymers and their synthetic counterparts, which is a fundamental problem in nanoscience," said Ronald Zuckermann, Director of the Biological Nanostructures Facility at the Molecular Foundry. "We can now translate fundamental sequence information from proteins to a non-natural polymer, which results in a robust synthetic nanomaterial with an atomically-defined structure."

The building blocks for peptoid polymers are cheap, readily available and generate a high yield of product, providing a huge advantage over other synthesis techniques. Zuckermann, instrumental in developing the Foundry's one-of-a-kind robotic synthesis capabilities, worked with his team of coauthors to form libraries of peptoid materials. After screening many candidates, the team landed upon the unique combination of polymer building blocks that spontaneously formed peptoid nanosheets in water.

Zuckermann and coauthor Christian Kisielowski reached another first by using the TEAM 0.5 microscope at the National Center for Electron Microscopy (NCEM) to observe individual polymer chains within the peptoid material, confirming the precise ordering of these chains into sheets and their unprecedented stability while being bombarded with electrons during imaging.

"The design of nature-inspired, functional polymers that can be assembled into membranes of large lateral dimensions marks a new chapter for materials synthesis with direct impact on Berkeley Lab's strategically relevant initiatives such as the Helios project or Carbon Cycle 2.0," said NCEM's Kisielowski. "The scientific possibilities that come with this achievement challenge our imagination, and will also help move electron microscopy toward direct imaging of soft materials."

"This new material is a remarkable example of molecular biomimicry on many levels, and will no doubt lead to many applications in device fabrication, nanoscale synthesis and imaging," Zuckermann added.

This research is reported in a paper appearing in the journal Nature Materials. Co-authoring the paper with Zuckermann and Kisielowski were Ki Tae Nam, Sarah Shelby, Phillip Choi, Amanda Marciel, Ritchie Chen, Li Tan, Tammy Chu, Ryan Mesch, Byoung-Chul Lee and Michael Connolly.

This work at the Molecular Foundry was supported by DOE's Office of Science and the Defense Threat Reduction Agency.

The Molecular Foundry is one of the five DOE Nanoscale Science Research Centers (NSRCs), premier national user facilities for interdisciplinary research at the nanoscale. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please visit http://nano.energy.gov.


Story Source:

The above story is based on materials provided by DOE/Lawrence Berkeley National Laboratory. Note: Materials may be edited for content and length.


Journal Reference:

  1. Ki Tae Nam, Sarah A. Shelby, Philip H. Choi, Amanda B. Marciel, Ritchie Chen, Li Tan, Tammy K. Chu, Ryan A. Mesch, Byoung-Chul Lee, Michael D. Connolly, Christian Kisielowski, Ronald N. Zuckermann. Free-floating ultrathin two-dimensional crystals from sequence-specific peptoid polymers. Nature Materials, 2010; DOI: 10.1038/nmat2742

Cite This Page:

DOE/Lawrence Berkeley National Laboratory. "Scientists create 'molecular paper' -- largest two-dimensional polymer crystal self-assembled in water." ScienceDaily. ScienceDaily, 15 April 2010. <www.sciencedaily.com/releases/2010/04/100414184222.htm>.
DOE/Lawrence Berkeley National Laboratory. (2010, April 15). Scientists create 'molecular paper' -- largest two-dimensional polymer crystal self-assembled in water. ScienceDaily. Retrieved October 2, 2014 from www.sciencedaily.com/releases/2010/04/100414184222.htm
DOE/Lawrence Berkeley National Laboratory. "Scientists create 'molecular paper' -- largest two-dimensional polymer crystal self-assembled in water." ScienceDaily. www.sciencedaily.com/releases/2010/04/100414184222.htm (accessed October 2, 2014).

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