In chemical weathering CO₂ from the atmosphere dissolved in rainwater reacts with rocks such as basalt or granite, dissolving them so that this atmospheric carbon then flows into the oceans, where a large proportion is 'trapped' in the bodies of marine organisms.

The team tested the idea that, as CO₂ warms the planet, the reactions involved in chemical weathering speed up, causing more CO₂ to be 'locked away', until, if CO₂ emissions decline, the climate begins to cool again. The Oxford team looked at evidence from the 'Ocean Anoxic Event 2' in the Late Cretaceous when volcanic activity spewed around 10 gigatonnes of CO₂ into the atmosphere every year for over 10,000 years. The researchers found that during this period chemical weathering increased, locking away more CO₂ as the world warmed and enabling the Earth to stabilise to a cooler climate within 300,000 years, up to four times faster than previously thought.

A report of the research is published in Nature Geoscience.

'Looking at this event is rather like imagining what the Earth would be like if humans disappeared tomorrow,' said Dr Philip Pogge von Strandmann of Oxford University's Department of Earth Sciences, who led the research. 'Volcanic CO₂ emissions in this period are similar to, if slightly slower than, current manmade emissions so that we can imagine a scenario in which, after human CO₂ emissions ceased, the planet's climate would start to recover and cool down. The bad news is that it's likely this would take around 300,000 years.'

Reconstructing a record of past chemical weathering is challenging because of how plants and animals take carbon out of the environment. To get around this the team used a recently-developed technique involving studying lithium isotopes in marine limestone (this lithium could only come from weathering and is not changed by biological organisms).

The Ocean Anoxic Event 2 is believed to have been caused by a massive increase in volcanic activity in one of three regions: the Caribbean, Madagascar, or the Solomon Islands. The event saw the temperature of seawater around the equator warm by about 3 degrees Celsius. It is thought that this warming caused around 53% of marine species to go extinct. Animals like turtles, fish, and ammonites were amongst those severely affected.

'Everyone remembers the mass extinction of land animals caused by the K-T meteorite impact 30 million years later, thought to be responsible for the demise of the dinosaurs, but in many ways this was just as devastating for marine life,' said Dr Pogge von Strandmann. 'Whilst nutrients from weathering caused a population boom of some species near the surface of the oceans, it also led to a loss of oxygen to the deeper ocean, killing off over half of all marine species and creating a 'dead zone' of decaying animals and plants. It's a scenario we wouldn't want to see repeated today.

'Our research is good news, showing that the Earth can recover up to four times faster than we thought from CO₂ emissions, but even if we stopped all emissions today this recovery would still take hundreds of thousands of years. We have to start doing something soon to remove CO₂ from the atmosphere if we don't want to see a repeat of the kind of mass extinctions that global warming has triggered in the past.'

The research was supported by the UK's Natural Environment Research Council.

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• Global Warming
• Climate
• Environmental Issues

• Fossils
• Origin of Life
• Early Climate

• Permian-Triassic extinction event
• Sedimentary rock
• Carbon cycle
• Volcanic rock
• Acid rain
• Ocean acidification