As is well known, the Earth is about 4.6 billion years old. No rocks exist, however, that are older than about 3.8 billion years. A sedimentary rock section in the Jack Hills of western Australia, more than 3 billion years old, contains within it zircons that were eroded from rocks as old as about 4.3 billion years, making these zircons, called Jack Hills zircons, the oldest recorded geological material on the planet.
In 2007 and 2008, two research papers reported in the journal Nature that a suite of zircons from the Jack Hills included diamonds, requiring a radical revision of early Earth history. The papers posited that the diamonds formed, somehow, before the oldest zircons -- that is, before 4.3 billion years ago -- and then were recycled repeatedly over a period of 1.2 billion years during which they were periodically incorporated into the zircons by an unidentified process.
Now a team of three researchers, two of whom are at the University of California, Riverside, has discovered using electron microscopy that the diamonds in question are not diamonds at all but broken fragments of a diamond-polishing compound that got embedded when the zircon specimen was prepared for analysis by the authors of the Nature papers.
"The diamonds are not indigenous to the zircons," said Harry Green, a research geophysicist and a distinguished professor of the Graduate Division at UC Riverside, who was involved in the research. "They are contamination. This, combined with the lack of diamonds in any other samples of Jack Hills zircons, strongly suggests that there are no indigenous diamonds in the Jack Hills zircons."
Study results appear online this week in the journal Earth and Planetary Science Letters.
"It occurred to us that a long-term history of diamond recycling with intermittent trapping into zircons would likely leave some sort of microstructural record at the interface between the diamonds and zircon," said Larissa Dobrzhinetskaya, a professional researcher in the Department of Earth Sciences at UCR and the first author of the research paper. "We reasoned that high-resolution electron microscopy of the material should be able to distinguish whether the diamonds are indeed what they have been believed to be."
Using an intensive search with high-resolution secondary-electron imaging and transmission electron microscopy, the research team confirmed the presence of diamonds in the Jack Hills zircon samples they examined but could readily identify them as broken fragments of diamond paste that the original authors had used to polish the zircons for examination. They also observed quartz, graphite, apatite, rutile, iron oxides, feldspars and other low-pressure minerals commonly included into zircon in granitic rocks.
"In other words, they are contamination from polishing with diamond paste that was mechanically injected into silicate inclusions during polishing" Green said.
The research was supported by a grant from the National Science Foundation.
Green and Dobrzhinetskaya were joined in the research by Richard Wirth at the Helmholtz Centre Potsdam, Germany.
Dobrzhinetskaya and Green planned the research project; Dobrzhinetskaya led the project; she and Wirth did the electron microscopy.
- Larissa Dobrzhinetskaya, Richard Wirth, Harry Green. Diamonds in Earthʼs oldest zircons from Jack Hills conglomerate, Australia, are contamination. Earth and Planetary Science Letters, 2014; 387: 212 DOI: 10.1016/j.epsl.2013.11.023
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