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Tiny step edges, big step for surface science

Date:
April 9, 2014
Source:
Vienna University of Technology, TU Vienna
Summary:
New experiments can explain the behavior of electrons at tiny step edges on titanium oxide surfaces. This is important for solar cell technology and novel, more effective catalysts.

Tiny step edges on tungsten oxide surfaces.
Credit: Image courtesy of Vienna University of Technology, TU Vienna

Experiments at the Vienna University of Technology can explain the behaviour of electrons at tiny step edges on titanium oxide surfaces. This is important for solar cell technology and novel, more effective catalysts.

It can be found in toothpaste, solar cells, and it is useful for chemical catalysts: titanium dioxide (TiO2) is an extremely versatile material. Alhough it is used for so many different applications, the behaviour of titanium oxide surfaces still surprises. Professor Ulrike Diebold and her team at the Vienna University of Technology managed to find out why oxygen atoms attach so well to tiny step edges at titanium oxide surfaces. Electrons accumulate precisely at these edges, allowing the oxygen atoms to connect more strongly. In solar cells, this effect should be avoided, but for catalysts this can be highly desirable.

Microscope Pictures of Titanium Oxide Surfaces

Titanium oxide is Ulrike Diebold's favourite material. In her latest publication, she and her team studied the behaviour of titanium oxide surfaces using scanning tunnelling microscopy and atomic force microscopy.

Titanium oxide can be used for solar cells. In the so-called Graetzel cell, an inexpensive but inefficient type of solar cell, it plays the central role. "In a solar cell, we want electrons to move freely and not attach to a particular atom," says Martin Setvin, first author of the publication, which has now appeared in the journal Angewandte Chemie.

The opposite is true for catalysts: For catalytic processes, it is often important that electrons attach to surface atoms. Only at places where such an additional electron is located can oxygen molecules attach to the titanium oxide surface and then take part in chemical reactions.

Electrons Distort the Crystal Structure

Usually, it takes a considerable amount of energy to have the electrons bond to a particular atom. "When an electron is localized at a titanium atom, the electric charge of the atom is changed, and due to electrostatic forces, the titanium oxide crystal is distorted," says Ulrike Diebold. To create this lattice distortion, energy has to be invested -- and therefore this effect does not usually occur by itself.

However, the surface of titanium oxide is never completely flat. On a microscopic scale, there are tiny steps and edges, many of them with a height of only one atomic layer. At these edges, electrons can localize quite easily. The atoms at the edge only have neighbours on one side, and therefore no major lattice distortions are created when these atoms receive an additional electron and change their charge state. "We have observed that oxygen molecules can connect to the surface precisely at these locations," says Diebold.

Better Solar Cells, More Efficient Catalysts

Important conclusions for technology can be drawn from this: for photovoltaics, such step edges should be avoided, for catalysts this newly discovered effect yields great opportunities. Surfaces could be microstructured to exhibit many such edges, making them extremely effective catalysts.


Story Source:

The above story is based on materials provided by Vienna University of Technology, TU Vienna. Note: Materials may be edited for content and length.


Journal Reference:

  1. Martin Setvin, Xianfeng Hao, Benjamin Daniel, Jiri Pavelec, Zbynek Novotny, Gareth S. Parkinson, Michael Schmid, Georg Kresse, Cesare Franchini, Ulrike Diebold. Charge Trapping at the Step Edges of TiO2Anatase (101). Angewandte Chemie International Edition, 2014; DOI: 10.1002/anie.201309796

Cite This Page:

Vienna University of Technology, TU Vienna. "Tiny step edges, big step for surface science." ScienceDaily. ScienceDaily, 9 April 2014. <www.sciencedaily.com/releases/2014/04/140409093949.htm>.
Vienna University of Technology, TU Vienna. (2014, April 9). Tiny step edges, big step for surface science. ScienceDaily. Retrieved September 30, 2014 from www.sciencedaily.com/releases/2014/04/140409093949.htm
Vienna University of Technology, TU Vienna. "Tiny step edges, big step for surface science." ScienceDaily. www.sciencedaily.com/releases/2014/04/140409093949.htm (accessed September 30, 2014).

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