New! Sign up for our free email newsletter.
Science News
from research organizations

Expanding the temperature range of lithium-ion batteries

Date:
June 19, 2019
Source:
American Chemical Society
Summary:
Electric cars struggle with extreme temperatures, mainly because of impacts on the electrolyte solutions in their lithium-ion batteries. Now, researchers have developed new electrolytes containing multiple additives that work better over a wide temperature range.
Share:
FULL STORY

Electric cars struggle with extreme temperatures, mainly because of impacts on the electrolyte solutions in their lithium-ion batteries. Now, researchers have developed new electrolytes containing multiple additives that work better over a wide temperature range. They report their results in ACS Applied Materials & Interfaces.

Lithium-ion batteries are widely used in cell phones, laptop computers and electric vehicles. The electrolyte solutions in these batteries conduct ions between the negative electrode (anode) and positive electrode (cathode) to power the battery. An indispensable component of most of these solutions, ethylene carbonate helps create a protective layer, preventing further decomposition of electrolyte components when they interact with the anode. However, ethylene carbonate has a high melting point, which limits its performance at low temperatures. Wu Xu and colleagues showed previously that they could extend the temperature range of lithium-ion batteries by partially replacing ethylene carbonate with propylene carbonate and adding cesium hexafluorophosphate. But they wanted to improve the temperature range even further, so that lithium-ion batteries could perform well from -40 to 140 F.

The researchers tested the effects of five electrolyte additives on the performance of lithium-ion batteries within this temperature range. They identified an optimized combination of three compounds that they added to their previous electrolyte solution. This new combination caused the formation of highly conductive, uniform and robust protective layers on both the anode and the cathode. Batteries containing the optimized electrolyte had greatly enhanced discharging performance at -40 F and long-term cycling stability at 77 F, along with slightly improved cycling stability at 140 F.


Story Source:

Materials provided by American Chemical Society. Note: Content may be edited for style and length.


Journal Reference:

  1. Bin Liu, Qiuyan Li, Mark H. Engelhard, Yang He, Xianhui Zhang, Donghai Mei, Chongmin Wang, Ji-Guang Zhang, Wu Xu. Constructing Robust Electrode/Electrolyte Interphases to Enable Wide Temperature Applications of Lithium-Ion Batteries. ACS Applied Materials & Interfaces, 2019; 11 (24): 21496 DOI: 10.1021/acsami.9b03821

Cite This Page:

American Chemical Society. "Expanding the temperature range of lithium-ion batteries." ScienceDaily. ScienceDaily, 19 June 2019. <www.sciencedaily.com/releases/2019/06/190619142555.htm>.
American Chemical Society. (2019, June 19). Expanding the temperature range of lithium-ion batteries. ScienceDaily. Retrieved June 25, 2024 from www.sciencedaily.com/releases/2019/06/190619142555.htm
American Chemical Society. "Expanding the temperature range of lithium-ion batteries." ScienceDaily. www.sciencedaily.com/releases/2019/06/190619142555.htm (accessed June 25, 2024).

Explore More

from ScienceDaily

RELATED STORIES