New! Sign up for our free email newsletter.
Science News
from research organizations

Cleaner air with a cold catalytic converter

A new catalyst can purify exhaust gases at room temperature

Date:
June 15, 2023
Source:
Eindhoven University of Technology
Summary:
Although passenger vehicle catalytic converters have been mandatory for over 30 years, there is still plenty of room for improvement. For instance, they only work correctly when the engine is sufficiently hot, which is not always the case, especially with hybrid vehicles. Researchers have now developed an improved catalyst that can properly purify exhaust gases even at room temperature.
Share:
FULL STORY

Although passenger vehicle catalytic converters have been mandatory for over 30 years, there is still plenty of room for improvement. For instance, they only work correctly when the engine is sufficiently hot, which is not always the case, especially with hybrid vehicles. Researchers from Eindhoven University of Technology (TU/e), together with colleagues from the University of Antwerp, have developed an improved catalyst that can properly purify exhaust gases even at room temperature. Their work is published in the journal Science on June 16th.

The so-called three-way catalytic converter in the exhaust system of a car consists of expensive materials and only works correctly when the exhaust gases have a temperature that is several hundred degrees Celsius.

As a result, when you start your car, or when you drive a hybrid car in which the petrol engine and electric motor alternate between driving the powertrain, the gases leaving the exhaust still contain toxic carbon monoxide. In a new Science article, scientists led by Emiel Hensen now show that by modifying the carrier material of the catalyst, it is possible to almost completely convert toxic carbon monoxide into carbon dioxide gas even at room temperature.

Noble needs

Automotive catalysts are made by depositing noble metals such as platinum, palladium, and rhodium on a substrate of the material cerium oxide, which is also known as ceria. However, noble metals are both rare and expensive. Researchers around the world are therefore working on methods to achieve the same or even better catalytic activity through the use of less of these materials.

For example, in a previous paper, Hensen's group at TU/e proved that by dispersing the noble metal in the form of single atoms leads to not only a reduction in material use, but under certain conditions, the catalyst also functions more efficiently.

New size view

In the PhD research project of lead author Valery Muravev, the researchers shifted their attention from the noble metal to the carrier material underneath (ceria in this case) to further improve the catalysts. They produced the ceria in different crystal sizes and deposited the noble metals as single atoms in the same step. Subsequently, they studied how well these combinations of materials managed to bind an extra oxygen atom to carbon monoxide.

Small ceria crystals of 4 nanometers in size turned out to remarkably improve the performance of the noble metal palladium under cold start conditions in the presence of excess carbon monoxide. This improved performance could be explained by a higher reactivity of the oxygen atoms at smaller ceria crystal sizes. Under more conventional conditions, 8 nanometers turned out to be the optimal size of ceria crystals needed to reach a high catalytic activity at temperatures below 100 degrees Celsius.

Wider significance

This research shows for the first time that when developing catalysts, it pays to look not only at the noble metals that have to do the work. In this case, varying the size of the particles that act as the carrier for the active materials offers an interesting new possibility to further improve catalysts and with those, improve the efficiency and specificity of the chemical reactions. This is also of importance for the development of processes to combine carbon dioxide from ambient air with green hydrogen to produce fuels or compounds for the production of sustainable plastics.

Together with the British company Johnson Matthey, which produces catalysts for the automotive industry, the researchers will now further explore how to translate this finding into new products.


Story Source:

Materials provided by Eindhoven University of Technology. Note: Content may be edited for style and length.


Journal Reference:

  1. Valery Muravev, Alexander Parastaev, Yannis van den Bosch, Bianca Ligt, Nathalie Claes, Sara Bals, Nikolay Kosinov, Emiel J. M. Hensen. Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts. Science, 2023; 380 (6650): 1174 DOI: 10.1126/science.adf9082

Cite This Page:

Eindhoven University of Technology. "Cleaner air with a cold catalytic converter." ScienceDaily. ScienceDaily, 15 June 2023. <www.sciencedaily.com/releases/2023/06/230615183125.htm>.
Eindhoven University of Technology. (2023, June 15). Cleaner air with a cold catalytic converter. ScienceDaily. Retrieved July 21, 2024 from www.sciencedaily.com/releases/2023/06/230615183125.htm
Eindhoven University of Technology. "Cleaner air with a cold catalytic converter." ScienceDaily. www.sciencedaily.com/releases/2023/06/230615183125.htm (accessed July 21, 2024).

Explore More

from ScienceDaily

RELATED STORIES