Featured Research

from universities, journals, and other organizations

Using Carbon Nanotubes For Molecular Transport

Date:
June 10, 2008
Source:
DOE/Lawrence Livermore National Laboratory
Summary:
Molecular transport across cellular membranes is essential to many of life's processes, for example electrical signaling in nerves, muscles and synapses. In biological systems, the membranes often contain a slippery inner surface with selective filter regions made up of specialized protein channels of sub-nanometer size. These pores regulate cellular traffic, allowing some of the smallest molecules in the world to traverse the membrane extremely quickly, while at the same time rejecting other small molecules and ions.

All the molecules in the carbon nanotube move fast. They do not stick to the surface of the nanotube because that surface is very slippery. The water molecules travel in chains because they interact with each other strongly via hydrogen bonds. These two effects (the slippery nanotube surface and formation of water molecule chains inside the nanotube) combine to produce this phenomenon of ultra-fast flow through carbon nanotubes.
Credit: Kwei-Yu Chu/LLNL

Molecular transport across cellular membranes is essential to many of life’s processes, for example electrical signaling in nerves, muscles and synapses.

In biological systems, the membranes often contain a slippery inner surface with selective filter regions made up of specialized protein channels of sub-nanometer size. These pores regulate cellular traffic, allowing some of the smallest molecules in the world to traverse the membrane extremely quickly, while at the same time rejecting other small molecules and ions.

Researchers at Lawrence Livermore National Laboratory are mimicking that process with manmade carbon nanotube membranes, which have pores that are 100,000 times smaller than a human hair, and were able to determine the rejection mechanism within the pores.

“Hydrophobic, narrow diameter carbon nanotubes can provide a simplified model of membrane channels by reproducing these critical features in a simpler and more robust platform,” said Olgica Bakajin, who led the LLNL team whose study appeared in the June 6 online edition of the journal Proceedings of the National Academy of Sciences.

In the initial discovery, reported in the May 19, 2006 issue of the journal Science, the LLNL team found that water molecules in a carbon nanotube move fast and do not stick to the nanotube’s super smooth surface, much like water moves through biological channels. The water molecules travel in chains – because they interact with each other strongly via hydrogen bonds.

“You can visualize it as mini-freight trains of chain-bonded water molecules flying at high speed through a narrow nanotube tunnel,” said Hyung Gyu Park, an LLNL postdoctoral researcher and a team member.

One of the most promising applications for carbon nanotube membranes is sea water desalination. These membranes will some day be able to replace conventional membranes and greatly reduce energy use for desalination.

In the recent study, the researchers wanted to find out if the membranes with 1.6 nanometer (nm) pores reject ions that make up common salts. In fact, the pores did reject the ions and the team was able to understand the rejection mechanism.

“Our study showed that pores with a diameter of 1.6nm on the average, the salts get rejected due to the charge at the ends of the carbon nanotubes,” said Francesco Fornasiero, an LLNL postdoctoral researcher, team member and the study’s first author

Fast flow through carbon nanotube pores makes nanotube membranes more permeable than other membranes with the same pore sizes. Yet, just like conventional membranes, nanotube membranes exclude ions and other particles due to a combination of small pore size and pore charge effects.

“While carbon nanotube membranes can achieve similar rejection as membranes with similarly sized pores, they will provide considerably higher permeability, which makes them potentially much more efficient than the current generation of membranes,” said Aleksandr Noy, a senior member of the LLNL team.

Researchers will be able to build better membranes when they can independently change pore diameter, charge and material that fills gaps between carbon nanotubes.


Story Source:

The above story is based on materials provided by DOE/Lawrence Livermore National Laboratory. Note: Materials may be edited for content and length.


Cite This Page:

DOE/Lawrence Livermore National Laboratory. "Using Carbon Nanotubes For Molecular Transport." ScienceDaily. ScienceDaily, 10 June 2008. <www.sciencedaily.com/releases/2008/06/080609141229.htm>.
DOE/Lawrence Livermore National Laboratory. (2008, June 10). Using Carbon Nanotubes For Molecular Transport. ScienceDaily. Retrieved October 22, 2014 from www.sciencedaily.com/releases/2008/06/080609141229.htm
DOE/Lawrence Livermore National Laboratory. "Using Carbon Nanotubes For Molecular Transport." ScienceDaily. www.sciencedaily.com/releases/2008/06/080609141229.htm (accessed October 22, 2014).

Share This



More Matter & Energy News

Wednesday, October 22, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Thanks, Marty McFly! Hoverboards Could Be Coming In 2015

Thanks, Marty McFly! Hoverboards Could Be Coming In 2015

Newsy (Oct. 21, 2014) If you've ever watched "Back to the Future Part II" and wanted to get your hands on a hoverboard, well, you might soon be in luck. Video provided by Newsy
Powered by NewsLook.com
Robots to Fly Planes Where Humans Can't

Robots to Fly Planes Where Humans Can't

Reuters - Innovations Video Online (Oct. 21, 2014) Researchers in South Korea are developing a robotic pilot that could potentially replace humans in the cockpit. Unlike drones and autopilot programs which are configured for specific aircraft, the robots' humanoid design will allow it to fly any type of plane with no additional sensors. Ben Gruber reports. Video provided by Reuters
Powered by NewsLook.com
Graphene Paint Offers Rust-Free Future

Graphene Paint Offers Rust-Free Future

Reuters - Innovations Video Online (Oct. 21, 2014) British scientists have developed a prototype graphene paint that can make coatings which are resistant to liquids, gases, and chemicals. The team says the paint could have a variety of uses, from stopping ships rusting to keeping food fresher for longer. Jim Drury reports. Video provided by Reuters
Powered by NewsLook.com
China Airlines Swanky New Plane

China Airlines Swanky New Plane

Buzz60 (Oct. 21, 2014) China Airlines debuted their new Boeing 777, and it's more like a swanky hotel bar than an airplane. Enjoy high-tea, a coffee bar, and a full service bar with cocktails and spirits, and lie-flat in your reclining seats. Sean Dowling (@SeanDowlingTV) has the details. Video provided by Buzz60
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:

Strange & Offbeat Stories


Space & Time

Matter & Energy

Computers & Math

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins