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Old Soles: 800-year-old Shoe Soles Yield Clues About Preservation Of Leather

Date:
March 17, 2009
Source:
American Chemical Society
Summary:
Ancient garbage can be like gold to archaeologists. During excavation of an 800-year-old trash dump in Lyon, France, scientists discovered the archaeological equivalent of golden shoe soles: A trove of leather soles of shoes, which is helping scientists understand how leather stays preserved in wet, oxygen-free environments.

A leather sole recovered from an archaeological trash dump in Lyon, France.
Credit: Pierre Alain Bayle

Ancient garbage can be like gold to archaeologists. During excavation of an 800-year-old trash dump in Lyon, France, scientists discovered the archaeological equivalent of golden shoe soles: A trove of leather soles of shoes, which is helping scientists understand how leather stays preserved in wet, oxygen-free environments.

That knowledge could aid restoration of other leather artifacts, according to a report on analysis of the old soles scheduled for the current issue of ACS' semi-monthly journal Analytical Chemistry.

In the article, Michel Bardet and colleagues point out that leather consists of collagen, a tough protein that can remain intact hundreds of thousands of years under ideal conditions. The French soles were buried in mud in the absence of oxygen — good conditions for preservation.

They used laboratory technology called nuclear magnetic resonance to compare composition of the ancient leather to modern leather. It turned out that tannin, which helps to preserve leather, had been washed out of the old soles and replaced by iron oxides. The iron oxides, which leached into the leather from surrounding soil, helped preserve the soles in the absence of tannins.


Story Source:

The above story is based on materials provided by American Chemical Society. Note: Materials may be edited for content and length.


Journal Reference:

  1. Bardet et al. Nuclear Magnetic Resonance and Electron Paramagnetic Resonance as Analytical Tools To Investigate Structural Features of Archaeological Leathers. Analytical Chemistry, 2009; 81 (4): 1505 DOI: 10.1021/ac802052a

Cite This Page:

American Chemical Society. "Old Soles: 800-year-old Shoe Soles Yield Clues About Preservation Of Leather." ScienceDaily. ScienceDaily, 17 March 2009. <www.sciencedaily.com/releases/2009/03/090309223456.htm>.
American Chemical Society. (2009, March 17). Old Soles: 800-year-old Shoe Soles Yield Clues About Preservation Of Leather. ScienceDaily. Retrieved July 24, 2014 from www.sciencedaily.com/releases/2009/03/090309223456.htm
American Chemical Society. "Old Soles: 800-year-old Shoe Soles Yield Clues About Preservation Of Leather." ScienceDaily. www.sciencedaily.com/releases/2009/03/090309223456.htm (accessed July 24, 2014).

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