Featured Research

from universities, journals, and other organizations

Improved carbon sponges to strip carbon dioxide from power plant exhausts

Date:
May 29, 2010
Source:
DOE/Lawrence Berkeley National Laboratory
Summary:
A new class of materials with a record-shattering internal surface area may have the right stuff to efficiently strip carbon dioxide from a power plant's exhaust.

More than a football field of surface area in the palm of your hand. Can scientists fashion metal-organic frameworks, seen in this illustration, into carbon-absorbing sponges? Will the material work in a power plant? Berkeley Lab scientists hope to find out soon.
Credit: Image courtesy of DOE/Lawrence Berkeley National Laboratory

Jeffrey Long's lab will soon host a round-the-clock, robotically choreographed hunt for carbon-hungry materials.

The Berkeley Lab chemist leads a diverse team of scientists whose goal is to quickly discover materials that can efficiently strip carbon dioxide from a power plant's exhaust, before it leaves the smokestack and contributes to climate change.

They're betting on a recently discovered class of materials called metal-organic frameworks that boast a record-shattering internal surface area. A sugar cube-sized piece, if unfolded and flattened, would more than blanket a football field. The crystalline material can also be tweaked to absorb specific molecules.

The idea is to engineer this incredibly porous compound into a voracious sponge that gobbles up carbon dioxide.

And they're going for speed. The scientists hope to discover this dream material in a breakneck three years, maybe sooner. To do this, they'll create an automated system that simultaneously synthesizes hundreds of metal-organic frameworks, then screens the most promising candidates for further refinement.

"Our discovery process will be up to 100 times faster than current techniques," says Long. "We need to quickly find next-generation materials that capture and release carbon without requiring a lot of energy."

Carbon capture is the first step in carbon capture and storage, a climate change mitigation strategy that involves pumping compressed carbon dioxide captured from large stationary sources into underground rock formations that can store it for geological time scales. Many scientists, including the United Nations' Intergovernmental Panel on Climate Change, believe that the technology is key to curbing the amount of carbon dioxide that enters the atmosphere. Fossil fuels such as coal and natural gas will likely remain cheap and plentiful energy sources for decades to come -- even with the continued development of renewable energy sources.

Carbon capture and storage is being tested on a large scale in only a few places worldwide. One of the biggest obstacles to industrial-scale implementation is its parasitic energy cost. Today's carbon capture materials, such as liquid amine scrubbers, sap a whopping 30 percent of the power generated by a power plant.

To overcome this, scientists are seeking alternatives that can be used again and again with minimal energy costs. It's a slow, finicky process. Promising materials such as metal-organic frameworks come in millions of variations, only a handful of which are conducive to capturing carbon. Finding just the right material may take years.

That could change. In early May, Long's team began negotiating a three-year, $3.6 million grant from the Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E) to supercharge the search.

"We want to run the discovery process very rapidly and find materials that only consume 10 percent of a power plant's energy," says Long, who's working with fellow Berkeley Lab scientists Maciej Haranczyk, Eric Masanet, Jeffrey Reimer, and Berend Smit on the project. Together, they'll create a state-of-the-art production line.

A robot will automatically synthesize hundreds of metal-organic frameworks and X-ray diffraction will offer a first-pass evaluation in the search for pure new materials. Magnetic resonance spectroscopy will then ferret out the materials with the pore size distribution best suited for carbon capture.

Next comes the big test: can it capture carbon dioxide from a flue gas? High-throughout gas sorption analysis conducted using new instrumentation built by Wildcat Discovery Technologies of San Diego, California will provide the answer.

Computer algorithms will constantly churn through the resulting data and help refine the next round of synthesis. Promising materials will also be assessed to determine if any ingredients are too expensive for large-scale commercialization.

"We don't want to discover a great material and find it's so expensive that no one will use it," says Long.

As a final test, the Electric Power Research Institute will predict the utility of the best new materials in an industrial-scale carbon capture process.

"We need to find the optimum range of metal-organic frameworks for each power plant," says Long. "Ultimately, this research is intended to lead to materials worthy of large-scale testing and commercialization."


Story Source:

The above story is based on materials provided by DOE/Lawrence Berkeley National Laboratory. Note: Materials may be edited for content and length.


Cite This Page:

DOE/Lawrence Berkeley National Laboratory. "Improved carbon sponges to strip carbon dioxide from power plant exhausts." ScienceDaily. ScienceDaily, 29 May 2010. <www.sciencedaily.com/releases/2010/05/100527171020.htm>.
DOE/Lawrence Berkeley National Laboratory. (2010, May 29). Improved carbon sponges to strip carbon dioxide from power plant exhausts. ScienceDaily. Retrieved September 30, 2014 from www.sciencedaily.com/releases/2010/05/100527171020.htm
DOE/Lawrence Berkeley National Laboratory. "Improved carbon sponges to strip carbon dioxide from power plant exhausts." ScienceDaily. www.sciencedaily.com/releases/2010/05/100527171020.htm (accessed September 30, 2014).

Share This



More Earth & Climate News

Tuesday, September 30, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Raw: Balloon Descends to Bottom of Croatian Cave

Raw: Balloon Descends to Bottom of Croatian Cave

AP (Sep. 29, 2014) An Austrian balloon pilot has succeeded in taking a balloon deep underground, a feat which he believes is a world first. (Sept. 29) Video provided by AP
Powered by NewsLook.com
Bodies Recovered from Japan Volcano Eruption

Bodies Recovered from Japan Volcano Eruption

AP (Sep. 29, 2014) Rescue crews finished recovering the remaining 27 bodies from atop Japan's Mount Ontake Monday. At least 31 people were killed Saturday in the mountain's first fatal volcanic event in modern history. (Sept. 29) Video provided by AP
Powered by NewsLook.com
Raw: Japan's Mount Ontake Erupts

Raw: Japan's Mount Ontake Erupts

AP (Sep. 27, 2014) A volcano erupted in central Japan on Saturday, sending a large plume of ash high into the sky and prompting a warning to climbers and others to avoid the area. (Sept. 27) Video provided by AP
Powered by NewsLook.com
California University Designs Sustainable Winery

California University Designs Sustainable Winery

Reuters - US Online Video (Sep. 27, 2014) Amid California's worst drought in decades, scientists at UC Davis design a sustainable winery that includes a water recycling system. Vanessa Johnston reports. Video provided by Reuters
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:

Strange & Offbeat Stories


Plants & Animals

Earth & Climate

Fossils & Ruins

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins