Featured Research

from universities, journals, and other organizations

A simple quantum dynamics problem?

Date:
July 15, 2010
Source:
American Institute of Physics
Summary:
New research provides the first real-time measurements of the time dependence of the individual steps of dissociation of a complex consisting of two rare gas atoms and a halogen molecule.

This is a step-by-step dissociation of Ne2Br2.
Credit: American Institute of Physics

Research reported in The Journal of Chemical Physics, which is published by the American Institute of Physics, provides the first real-time measurements of the time dependence of the individual steps of dissociation of a complex consisting of two rare gas atoms and a halogen molecule.

Related Articles


"The goal of this work is to provide a test case for quantum dynamics theory," says author Kenneth C. Janda of the University of California, Irvine. "It is a problem that is easy, but not too easy, in the sense that a fundamental quantum dynamics explanation is within reach."

Researchers cooled a mixture of helium, neon, and bromine by spraying it through a nozzle, resulting in a stream of gas particles traveling at the same speed. This created a very low temperature in a moving frame of reference -- the particles were stationary relative to one another and condensed to form Ne2Br2 tetrahedral complexes. After the bromine molecule was excited with a laser pulse, the dissociation of the complex over a period of tens of picoseconds was observed spectroscopically. Adding 16 quanta of vibrational energy to the bromine-stretching vibration resulted in rapid direct dissociation. The two Ne atoms dissociated without interacting with each other. However, with slightly higher vibrational excitation, a 23-quanta boost, the bromine anharmonicity led to sharing of the kinetic energy between the Ne atoms and a much more complicated dissociation mechanism.

"For 23 quanta, the first transfer of vibration fails to knock off one of the neon atoms 80 percent of the time," says Janda. "Instead a tiny liquid drop is formed, allowing a neon atom to move in a direct line with the bromine atoms. The next vibration shoots it off like a pool stick hitting the cue ball."


Story Source:

The above story is based on materials provided by American Institute of Physics. Note: Materials may be edited for content and length.


Journal Reference:

  1. Jordan M. Pio, Molly A. Taylor, Wytze E. van der Veer, Craig R. Bieler, Jose A. Cabrera, Kenneth C. Janda. Real-time dissociation dynamics of the Ne2Br2 van der Waals complex. The Journal of Chemical Physics, 2010; 133 (1): 014305 DOI: 10.1063/1.3456550

Cite This Page:

American Institute of Physics. "A simple quantum dynamics problem?." ScienceDaily. ScienceDaily, 15 July 2010. <www.sciencedaily.com/releases/2010/07/100714094617.htm>.
American Institute of Physics. (2010, July 15). A simple quantum dynamics problem?. ScienceDaily. Retrieved October 30, 2014 from www.sciencedaily.com/releases/2010/07/100714094617.htm
American Institute of Physics. "A simple quantum dynamics problem?." ScienceDaily. www.sciencedaily.com/releases/2010/07/100714094617.htm (accessed October 30, 2014).

Share This



More Matter & Energy News

Thursday, October 30, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Mind-Controlled Prosthetic Arm Restores Amputee Dexterity

Mind-Controlled Prosthetic Arm Restores Amputee Dexterity

Reuters - Innovations Video Online (Oct. 29, 2014) A Swedish amputee who became the first person to ever receive a brain controlled prosthetic arm is able to manipulate and handle delicate objects with an unprecedented level of dexterity. The device is connected directly to his bone, nerves and muscles, giving him the ability to control it with his thoughts. Matthew Stock reports. Video provided by Reuters
Powered by NewsLook.com
Robots Get Funky on the Dance Floor

Robots Get Funky on the Dance Floor

AP (Oct. 29, 2014) Dancing, spinning and fighting robots are showing off their agility at "Robocomp" in Krakow. (Oct. 29) Video provided by AP
Powered by NewsLook.com
Saharan Solar Project to Power Europe

Saharan Solar Project to Power Europe

Reuters - Business Video Online (Oct. 29, 2014) A solar energy project in the Tunisian Sahara aims to generate enough clean energy by 2018 to power two million European homes. Matt Stock reports. Video provided by Reuters
Powered by NewsLook.com
Lowe's Testing Robot Sales Assistants in California Store

Lowe's Testing Robot Sales Assistants in California Store

Buzz60 (Oct. 29, 2014) Lowe’s is testing out what it’s describing as a robotic shopping assistant in one of its Orchard Supply Hardware Stores in California. Jen Markham explains. Video provided by Buzz60
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:

Breaking News:

Strange & Offbeat Stories


Space & Time

Matter & Energy

Computers & Math

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile: iPhone Android Web
Follow: Facebook Twitter Google+
Subscribe: RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins