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Lead-free piezoelectric materials of the future

September 27, 2010
American Institute of Physics
Over the past 60 years, lead zirconate titanate, or PZT, has been the material of choice for piezoelectric applications from ink jet printers to gas grill igniters. Despite this success, many scientists would like to find a more environmentally-friendly, lead-free material. The theoretical potential of another class of materials has now been shown.

Piezoelectric materials have fantastic properties: squeeze them and they generate an electrical field. And vice-versa, they contract or expand when jolted with an electrical pulse. With a name derived from the Greek word meaning to squeeze or press, the piezoelectric effect was just a curiosity after it was discovered in several crystals in 1880. But in 1917, a quartz piezoelectric crystal was at the heart of the world's first submarine-detecting sonar.

Piezoelectric materials really took off after the 1950s, with the development of a superior man-made piezoelectric ceramic crystal: lead zirconate titanate, or PZT (the initials of its chemical symbols). Over the past 60 years, PZT has been essential for myriad high-tech applications: from inkjet printers to digital camera shutters, ultrasonic imagers, fuel injector actuators, and igniters for gas barbecue grills.

Despite this success, many scientists now want to replace PZT with some as yet undiscovered lead-free material that would be more environmentally benign and that would enable new piezoelectric applications in biological settings. To date, however, no suitable successors have been found. Candidates are typically too feeble in their piezoelectric effect and/or physical durability.

A Swiss scientist, Dragan Damjanovic, thinks researchers should be looking more broadly. He says nearly all of today's efforts are focused on materials whose ions and electrons -- the ultimate source of the piezoelectric effect -- behave in a particular manner, called polarization rotation. His theoretical calculations have shown that another, overlooked behavior -- polarization extension, present in other classes of materials -- can also generate an enhanced piezoelectric effect.

An article by Damjanovic in the journal Applied Physics Letters, which is published by the American Institute of Physics, details his ideas and supporting evidence. In particular, he proposes a particular type of phase diagram that he believes will lead to improved, lead-free piezoelectric materials.

"What I have done is at odds with the dominant thinking," Damjanovic admits. "But I offer a different approach to an important problem."

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Journal Reference:

  1. Damjanovic et al. A morphotropic phase boundary system based on polarization rotation and polarization extension. Applied Physics Letters, 2010; 97 (6): 062906 DOI: 10.1063/1.3479479

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American Institute of Physics. "Lead-free piezoelectric materials of the future." ScienceDaily. ScienceDaily, 27 September 2010. <>.
American Institute of Physics. (2010, September 27). Lead-free piezoelectric materials of the future. ScienceDaily. Retrieved March 28, 2017 from
American Institute of Physics. "Lead-free piezoelectric materials of the future." ScienceDaily. (accessed March 28, 2017).