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A way to surmount supercooling

June 28, 2021
Osaka University
Researchers study the use of nanoparticles to induce crystallization of supercooled aqueous solutions to clathrate hydrates. On the basis of scanning electron microscopy images, they discovered that silver nanoparticles are much more effective compared with palladium or gold. This research may open the way for new latent heat energy storage materials via enhanced supercooling control.

Scientists at Osaka University, Panasonic Corporation, and Waseda University used scanning electron microscopy (SEM) and X-ray absorption spectroscopy to determine which additives induce crystallization in supercooled aqueous solutions. This work may lead to the development of new energy storage materials based on latent heat.

If you put a bottle of water into the freezer, you will expect to pull out a solid cylinder of ice after a few hours. However, if the water has very few impurities and left undisturbed, it may not be frozen, and instead remain as a supercooled liquid. Be careful, because this state is very unstable, and the water will crystallize quickly if shaken or impurities are added -- as many YouTube videos will attest. Supercooling is a phenomenon in which an aqueous solution maintains its liquid state without solidifying, even though its temperature is below the freezing point. Although many studies have been done on additives that trigger the freezing of supercooling liquids, the details of the mechanism are unknown. One potential application might be latent heat storage materials, which rely on freezing and melting to capture and later release heat, like a reusable freezer pack.

Now, a team of researchers led by Osaka University has shown that silver nanoparticles are very effective at inducing crystallization in clathrate hydrates. Clathrate hydrates physically look like ice and are composed of hydrogen-bonded water cages with guest molecules inside. "Using SEM with the freeze-fracture replica method, we captured the moment when a nascent cluster enveloped a silver nanoparticle in the aqueous solution of latent heat storage materials," corresponding author Professor Takeshi Sugahara explains. This occurs because the nanoparticles serve as a "seed," or nucleation site, for tiny clusters to form. Once this gets started, the remaining solute and water molecules can quickly form additional clusters and then cluster densification leads to the crystallization. The researchers found that while silver nanoparticles tended to accelerate the formation of these clusters, other metal nanoparticles, such as palladium, gold, and iridium do not promote crystallization. "The supercooling suppression effect obtained in the present study will contribute to achieve the practical use of clathrate hydrates as latent heat storage materials," Professor Sugahara says. Material design guidelines for enhanced supercooling control, as described in this study, may lead to the application of latent heat storage materials in solar energy and heat recovery technologies with improved efficiency.

Story Source:

Materials provided by Osaka University. Note: Content may be edited for style and length.

Journal Reference:

  1. Hironobu Machida, Takeshi Sugahara, Izumi Hirasawa. The moment of initial crystallization captured on functionalized nanoparticles. Communications Materials, 2021; 2 (1) DOI: 10.1038/s43246-021-00171-w

Cite This Page:

Osaka University. "A way to surmount supercooling." ScienceDaily. ScienceDaily, 28 June 2021. <>.
Osaka University. (2021, June 28). A way to surmount supercooling. ScienceDaily. Retrieved May 26, 2024 from
Osaka University. "A way to surmount supercooling." ScienceDaily. (accessed May 26, 2024).

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