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Neutrons rule the roost for cage-free lithium ions

April 16, 2024
DOE/Oak Ridge National Laboratory
Scientists using neutrons set the first benchmark (one nanosecond) for a polymer-electrolyte and lithium-salt mixture. Findings could boost power and safety for lithium batteries.

An international team of scientists found a way to improve battery design that could produce safer, more powerful lithium batteries.

The team used quasi-elastic neutron scattering at Oak Ridge National Laboratory to set the first benchmark, one-nanosecond, or one billionth of a second, for a mixture of lithium salt and an organic polymer electrolyte.

"It all comes down to the study of materials," said Eugene Mamontov, ORNL Chemical Spectroscopy group leader. "And polymer electrolytes won't catch fire the way liquid electrolytes do in lithium batteries."

The team used the neutron technique to validate computer simulations, ending a long-standing debate about how long it takes lithium ions to break free from tiny cages created by polymer electrolytes. The rate at which ions in any battery break free from such environments, or solvation cages in polymer electrolytes, helps determine how energy flows through the battery. Polymer electrolytes could enable more energy-dense electrodes, like lithium metal, resulting in more powerful lithium batteries.

The findings also open doors for rapidly screening new battery materials at ORNL. "Neutrons are highly sensitive to hydrogen, which is present in virtually all electrolytes. This allowed us to see how it moved in the system and understand polymer electrolyte dynamics at an unprecedented level of detail. We couldn't have pinned down the time and length any other way," said Naresh Osti, ORNL neutron scattering scientist.

"Naresh and Eugene's interpretation of neutron data from the experiment at ORNL opened our eyes to understanding the extent to which lithium ions are caged in polymer electrolytes. Our findings suggest this general approach will apply to liquid electrolytes," said Nitash Balsara, Charles W. Tobias Professor of Electrochemistry at the University of California, Berkeley. 

Story Source:

Materials provided by DOE/Oak Ridge National Laboratory. Original written by Sumner Brown Gibbs. Note: Content may be edited for style and length.

Journal Reference:

  1. Neel J. Shah, Chao Fang, Naresh C. Osti, Eugene Mamontov, Xiaopeng Yu, Jaeyong Lee, Hiroshi Watanabe, Rui Wang, Nitash P. Balsara. Nanosecond solvation dynamics in a polymer electrolyte for lithium batteries. Nature Materials, 2024; DOI: 10.1038/s41563-024-01834-y

Cite This Page:

DOE/Oak Ridge National Laboratory. "Neutrons rule the roost for cage-free lithium ions." ScienceDaily. ScienceDaily, 16 April 2024. <>.
DOE/Oak Ridge National Laboratory. (2024, April 16). Neutrons rule the roost for cage-free lithium ions. ScienceDaily. Retrieved May 27, 2024 from
DOE/Oak Ridge National Laboratory. "Neutrons rule the roost for cage-free lithium ions." ScienceDaily. (accessed May 27, 2024).

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