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Shining new light on air pollutants using entangled porous frameworks

Date:
January 26, 2011
Source:
Institute for Integrated Cell-Material Sciences, Kyoto University
Summary:
Certain types of pollution monitoring may soon become considerably easier. Scientists have shown that a newly-formulated entangled framework of porous crystals (porous coordination polymers, or PCPs) can not only capture a variety of common air pollutants, but that the mixtures then glow in specific, easily-detected colors.
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Certain types of pollution monitoring may soon become considerably easier. A group of researchers centered at Kyoto University has shown in a recent Nature Communications paper that a newly-formulated entangled framework of porous crystals (porous coordination polymers, or PCPs) can not only capture a variety of common air pollutants, but that the mixtures then glow in specific, easily-detected colors.

Lead author for the paper was Dr. Yohei Takashima.

Until now, chemical sensors have generally needed to be custom-designed to recognize specific compounds, and a separate transmission mechanism was required in order to "see" that a particular molecule had indeed been successfully captured.

"We have created what amount to be interlocking jungle-gyms, that move relative to each other and are therefore able to capture molecules of varying sizes," explained Dr. Shuhei Furukawa of Kyoto University's Institute for Integrated Cell-Material Sciences (iCeMS).

This naphthalenediimide-based PCP, known as NDI, expands and contracts to confine air-born volatile organic compounds (VOCs) such as benzene, toluene, xylene, anisole, and iodobenzene, which are common pollutants in the lower atmosphere.

"When exposed to ultraviolet light, the NDI-VOC interaction luminesces in an unusually wide range of colors, sufficiently intense to be observed even with the naked eye," elaborated iCeMS Professor and deputy director, Susumu Kitagawa.

These findings, including contributions from Dr. Virginia Martínez Martínez at the Universidad del País Vasco in Bilbao, open the door to the development of a new range of portable, solid-state pollution detectors, and possibly even new types of light sources.


Story Source:

The above post is reprinted from materials provided by Institute for Integrated Cell-Material Sciences, Kyoto University. Note: Materials may be edited for content and length.


Journal Reference:

  1. Yohei Takashima, Virginia Martínez Martínez, Shuhei Furukawa, Mio Kondo, Satoru Shimomura, Hiromitsu Uehara, Masashi Nakahama, Kunihisa Sugimoto, Susumu Kitagawa. Molecular decoding using luminescence from an entangled porous framework. Nature Communications, 2011; 2 (1): 168 DOI: 10.1038/ncomms1170

Cite This Page:

Institute for Integrated Cell-Material Sciences, Kyoto University. "Shining new light on air pollutants using entangled porous frameworks." ScienceDaily. ScienceDaily, 26 January 2011. <www.sciencedaily.com/releases/2011/01/110125111000.htm>.
Institute for Integrated Cell-Material Sciences, Kyoto University. (2011, January 26). Shining new light on air pollutants using entangled porous frameworks. ScienceDaily. Retrieved August 30, 2015 from www.sciencedaily.com/releases/2011/01/110125111000.htm
Institute for Integrated Cell-Material Sciences, Kyoto University. "Shining new light on air pollutants using entangled porous frameworks." ScienceDaily. www.sciencedaily.com/releases/2011/01/110125111000.htm (accessed August 30, 2015).

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