Featured Research

from universities, journals, and other organizations

Bleach in the Icelandic Volcanic Cloud

Date:
May 27, 2011
Source:
Max Planck Institute for Chemistry
Summary:
Chlorine in the ash plume of the Icelandic volcano Eyjafjallajökull attacked atmospheric trace gases. One year after the Eyjafjallajökull volcano in Iceland brought European air traffic to a standstill its ash plume revealed a surprising scientific finding: Researchers found that the ash plume contained not only the common volcanic gas sulfur dioxide, but also free chlorine radicals. Chlorine radicals are extremely reactive and even small amounts can have a profound impact on local atmospheric chemistry. The findings give solid evidence of volcanic plume chlorine radical chemistry and allowed calculations of chlorine radical concentrations.

CARIBIC flight track from Frankfurt to the British Isles on May 16. The dots indicate air sampling locations. The colored regions depict the extent of the volcanic ash cloud as calculated using meteorological models, with red/yellow indicating high and purple low amounts of particles.
Credit: Figure taken from Baker et al., 2011 (GRL).

One year after the Eyjafjallajökull volcano in Iceland brought European air traffic to a standstill its ash plume revealed a surprising scientific finding: Researchers at the Max Planck Institute for Chemistry in Mainz found that the ash plume contained not only the common volcanic gas sulfur dioxide, but also free chlorine radicals. Chlorine radicals are extremely reactive and even small amounts can have a profound impact on local atmospheric chemistry. The findings, which will be published in "Geophysical Research Letters" give solid evidence of volcanic plume chlorine radical chemistry and allowed calculations of chlorine radical concentrations.

It has been known for some time that volcanic eruptions emit chlorine-containing gases, causing scientists to suspect that highly reactive chlorine radicals could also be present. However, sufficient experimental evidence proved elusive. That changed when researchers analyzed air collected in the ash cloud emitted by the Eyjafjallajökull volcano. During three special flights conducted by Lufthansa in spring 2010 using the CARIBIC atmospheric measurement container, researchers collected air samples which they brought back to their laboratory in Mainz for analysis. Among the compounds they looked for were hydrocarbons.

"Each volcano has its own character," says Angela Baker, lead author of the paper. "We found that hydrocarbon concentrations were up to 70% lower inside the Eyjafjallajökull ash cloud than outside. Reaction with chlorine radicals was the only realistic explanation for the hydrocarbon losses. And further investigation confirmed that free chlorine radicals were the cause." The scientists calculated concentrations of up to 66,000 chlorine atoms per cubic centimeter of air. While modest compared to concentrations of other gases, chlorine radicals are normally absent, and it does not take much of these very reactive atoms to have a noticeable impact on atmospheric chemistry.

Hydrocarbons like propane and butane can be found even in the cleanest and most remote parts of the lower atmosphere. Normally they are removed when they react with hydroxyl radicals, but they react many times faster with chlorine radicals. In doing so the chlorine reactions leave their specific "signature" on the mixture of hydrocarbons in the air. This signature can, in turn, be used to calculate how many chlorine radicals were present. The Max Planck scientists who calculated volcanic ash cloud chlorine radical concentrations for the first time anticipate that similar results will be found in plumes from other volcanoes, such as the currently erupting Grimsvötn. They also hope that their method will be used during future studies to identify and understand volcanic chlorine radical chemistry.


Story Source:

The above story is based on materials provided by Max Planck Institute for Chemistry. Note: Materials may be edited for content and length.


Journal Reference:

  1. Angela K. Baker, Armin Rauthe-Schöch, Tanja J. Schuck, Carl A. M. Brenninkmeijer, Peter F. J. van Velthoven, Adam Wisher, David E. Oram. Investigation of chlorine radical chemistry in the Eyjafjallajökull volcanic plume using observed depletions in non-methane hydrocarbons. Geophysical Research Letters, 2011 DOI: 10.1029/2011GL047571

Cite This Page:

Max Planck Institute for Chemistry. "Bleach in the Icelandic Volcanic Cloud." ScienceDaily. ScienceDaily, 27 May 2011. <www.sciencedaily.com/releases/2011/05/110527080327.htm>.
Max Planck Institute for Chemistry. (2011, May 27). Bleach in the Icelandic Volcanic Cloud. ScienceDaily. Retrieved October 20, 2014 from www.sciencedaily.com/releases/2011/05/110527080327.htm
Max Planck Institute for Chemistry. "Bleach in the Icelandic Volcanic Cloud." ScienceDaily. www.sciencedaily.com/releases/2011/05/110527080327.htm (accessed October 20, 2014).

Share This



More Earth & Climate News

Monday, October 20, 2014

Featured Research

from universities, journals, and other organizations


Featured Videos

from AP, Reuters, AFP, and other news services

Raw: Powerful Hurricane Gonzalo Heads to Bermuda

Raw: Powerful Hurricane Gonzalo Heads to Bermuda

AP (Oct. 17, 2014) — Hurricane Gonzalo pounded Bermuda with wind and heavy surf on Friday, bearing down on the tiny British territory as a powerful Category 3 storm that could raise coastal seas as much as 10 feet. (Oct. 17) Video provided by AP
Powered by NewsLook.com
So, Kangaroos Didn't Always Hop

So, Kangaroos Didn't Always Hop

Newsy (Oct. 16, 2014) — Researchers believe an extinct kangaroo species weighed 500 pounds or more and couldn't hop. Video provided by Newsy
Powered by NewsLook.com
Hurricane Gonzalo Is A Category 4 And Heading To Bermuda

Hurricane Gonzalo Is A Category 4 And Heading To Bermuda

Newsy (Oct. 16, 2014) — Powerful hurricane could hit Bermuda this weekend, and even if it misses it will likely do some damage. Video provided by Newsy
Powered by NewsLook.com
The Largest Volcano In Centuries Is Spewing Toxic Gas

The Largest Volcano In Centuries Is Spewing Toxic Gas

Newsy (Oct. 16, 2014) — One of the largest volcanic eruptions in centuries is occurring on Iceland. The volcano Bardarbunga is producing high levels of sulfur dioxide. Video provided by Newsy
Powered by NewsLook.com

Search ScienceDaily

Number of stories in archives: 140,361

Find with keyword(s):
 
Enter a keyword or phrase to search ScienceDaily for related topics and research stories.

Save/Print:
Share:  

Breaking News:

Strange & Offbeat Stories

 

Plants & Animals

Earth & Climate

Fossils & Ruins

In Other News

... from NewsDaily.com

Science News

Health News

Environment News

Technology News



Save/Print:
Share:  

Free Subscriptions


Get the latest science news with ScienceDaily's free email newsletters, updated daily and weekly. Or view hourly updated newsfeeds in your RSS reader:

Get Social & Mobile


Keep up to date with the latest news from ScienceDaily via social networks and mobile apps:

Have Feedback?


Tell us what you think of ScienceDaily -- we welcome both positive and negative comments. Have any problems using the site? Questions?
Mobile iPhone Android Web
Follow Facebook Twitter Google+
Subscribe RSS Feeds Email Newsletters
Latest Headlines Health & Medicine Mind & Brain Space & Time Matter & Energy Computers & Math Plants & Animals Earth & Climate Fossils & Ruins