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Scanning tunneling microscopy: Computer simulations sharpen insights into molecules

Date:
November 27, 2014
Source:
Forschungszentrum Juelich
Summary:
The resolution of scanning tunneling microscopes can be improved dramatically by attaching small molecules or atoms to their tip. The resulting images were the first to show the geometric structure of molecules and have generated a lot of interest among scientists over the last few years.
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Simulations of different types of scanning probe microscopy with atomic-scale sensors: Simulated atomic force microscopy image (left), simulated scanning tunnelling microscopy image (centre), simulation of an inelastic electron tunnelling spectroscopy image (right).
Credit: Hapala/Temirov/Tautz/Jelínek, Physical Review Letters, Copyright 2014 by The American Physical Society

The resolution of scanning tunnelling microscopes can be improved dramatically by attaching small molecules or atoms to their tip. The resulting images were the first to show the geometric structure of molecules and have generated a lot of interest among scientists over the last few years. Scientists from Forschungszentrum Jülich and the Academy of Sciences of the Czech Republic in Prague have now used computer simulations to gain deeper insights into the physics of these new imaging techniques. One of these techniques was presented in the journal Science by American scientists this spring. The results have now been published in the journal Physical Review Letters.

"A comparison between the experimental results and our simulations shows excellent agreement and that, therefore, our theoretical model is able to explain the mechanism behind the microscopic images in this family of techniques," says Prof. Tautz from Forschungszentrum Jülich. "This comparison is essential for analysing the images."

Together with his colleagues from the Peter Grünberg Institute (PGI-3), in 2008 Tautz introduced the method of attaching single molecules -- initially hydrogen molecules, later molecules such as carbon monoxide -- to the tip of a scanning tunnelling microscope and using them as extremely sensitive measuring probes. The scientific community responded with great interest to this method, and the technique has since been continuously refined. It enables scanning tunnelling microscopes to be used as a kind of atomic force microscope that is able to image the geometric structure of molecules with unprecedented accuracy.

"The valence charge clouds of complex organic molecules often spread over the entire molecule, thus concealing its atomic structure," says Tautz. Flexibly bound molecules at the microscope tip can be utilized as tailor-made sensors and signal transducers that are able to make the atomic structure visible nevertheless.

In the last few years, such atomic sensors have also proven useful for work with atomic force microscopes. Then, in May 2014, scientists from the University of California, Irvine, showed for the first time that these sensors can also be used to improve signals in a related imaging mode known as inelastic electron tunnelling spectroscopy. In this case, it is the vibration of the sensor molecule against the microscope tip that reacts sensitively to the surface potential of the scanned sample.

"Our calculations show the effect of the electrostatic forces on the high-resolution AFM, STM, and IETS images," explains Dr. Pavel Jelínek from the Institute of Physics at the Academy of Sciences of the Czech Republic in Prague. "We believe that the results of this work are an important contribution to the use of inelastic electron tunnelling spectroscopy that will allow the technique to be used as an additional source of information in materials science and to derive additional parameters from the images."


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Journal References:

  1. Prokop Hapala, Ruslan Temirov, F. Stefan Tautz, Pavel Jelínek. Origin of High-Resolution IETS-STM Images of Organic Molecules with Functionalized Tips. Phys. Rev. Lett., 25 November 2014 DOI: 10.1103/PhysRevLett.113.226101
  2. Prokop Hapala, Georgy Kichin, Christian Wagner, F. Stefan Tautz, Ruslan Temirov, Pavel Jelínek. Mechanism of high-resolution STM/AFM imaging with functionalized tips. Physical Review B, 2014; 90 (8) DOI: 10.1103/PhysRevB.90.085421

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Forschungszentrum Juelich. "Scanning tunneling microscopy: Computer simulations sharpen insights into molecules." ScienceDaily. ScienceDaily, 27 November 2014. <www.sciencedaily.com/releases/2014/11/141127082305.htm>.
Forschungszentrum Juelich. (2014, November 27). Scanning tunneling microscopy: Computer simulations sharpen insights into molecules. ScienceDaily. Retrieved March 30, 2017 from www.sciencedaily.com/releases/2014/11/141127082305.htm
Forschungszentrum Juelich. "Scanning tunneling microscopy: Computer simulations sharpen insights into molecules." ScienceDaily. www.sciencedaily.com/releases/2014/11/141127082305.htm (accessed March 30, 2017).