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A device to control 'color' of electrons in graphene provides path to future electronics

August 29, 2016
Penn State Materials Research Institute
A device made of bilayer graphene is one step forward in a new field of physics called valleytronics.

This is a scanned electron micrograph of a device used in this experiment. Thin sheets of graphene and hexagonal Boron Nitride are stacked and shaped by electron beam lithography to create this device. The purple layer is the bilayer graphene sheet. The bottom pair of split gates (dark squares) are made of multi-layer graphene. The top pair of split gates (gold bars) are made of gold. The one-dimensional wires live in the gap created by the split gates.
Credit: Zhu, Penn State

A device made of bilayer graphene, an atomically thin hexagonal arrangement of carbon atoms, provides experimental proof of the ability to control the momentum of electrons and offers a path to electronics that could require less energy and give off less heat than standard CMOS transistors. It is one step forward in a new field of physics called valleytronics.

"Current silicon-based transistor devices rely on the charge of electrons to turn the device on or off, but many labs are looking at new ways to manipulate electrons based on other variables, called degrees of freedom," said Jun Zhu, associate professor of physics at Penn State, who directed the research. "Charge is one degree of freedom. Electron spin is another, and the ability to build transistors based on spin, called spintronics, is still in the development stage. A third electronic degree of freedom is the valley state of electrons, which is based on their energy in relation to their momentum."

Think of electrons as cars and the valley states as blue and red colors, Zhu suggested, just as a way to differentiate them. Inside a sheet of bilayer graphene, electrons will normally occupy both red and blue valley states and travel in all directions. The device her Ph.D. student, Jing Li, has been working on can make the red cars go in one direction and the blue cars in the opposite direction.

"The system that Jing created puts a pair of gates above and below a bilayer graphene sheet. Then he adds an electric field perpendicular to the plane," Zhu said.

"By applying a positive voltage on one side and a negative voltage on the other, a bandgap opens in bilayer graphene, which it doesn't normally have. In the middle, between the two sides, we leave a physical gap of about 70 nanometers," Li explained.

Inside this gap lives one-dimensional metallic states, or wires, that are color-coded freeways for electrons. The red cars travel in one direction and the blue cars travel in the opposite direction. In theory, colored electrons could travel unhindered along the wires for a long distance with very little resistance. Smaller resistance means power consumption is lower in electronic devices and less heat is generated. Both power consumption and thermal management are challenges in current miniaturized devices.

"Our experiments show that the metallic wires can be created," Li said. "Although we are still a long way from applications."

Zhu added, "It's quite remarkable that such states can be created in the interior of an insulating bilayer graphene sheet, using just a few gates. They are not yet resistance-free, and we are doing more experiments to understand where resistance might come from. We are also trying to build valves that control the electron flow based on the color of the electrons. That's a new concept of electronics called valleytronics."

Li worked closely with the technical staff of Penn State's nanofabrication facility to turn the theoretical framework into a working device.

"The alignment of the top and bottom gates was crucial and not a trivial challenge. The state of the art electron beam lithography capabilities at the Penn State Nanofabrication Laboratory allowed Jing to create this novel device with nanoscale features," says Chad Eichfeld, Nanolithography Engineer.

Their paper, titled "Gate-controlled topological conducting channels in bilayer graphene," appears online today, August 29, in the journal Nature Nanotechnology. Additional authors include Ke Wang and Yafei Ren and their advisor Zenhua Qiao of University of Science and Technology of China, who performed numerical studies to model the behavior of the wires. The high-quality hexagonal Boron Nitride crystals used in the experiment came from Kenji Watanabe and Takashi Taniguchi of National Institute for Material Science, Japan. Two undergraduate students, Kenton McFaul and Zachary Zern, contributed to the research.

Funding was provided by the U.S. Office of Naval Research, the National Science Foundation and funding agencies in China and Japan. Kenton McFaul, a visiting student from Grove City College, was supported by a Research Experience for Undergraduates grant from the NSF NNIN. Jun Zhu is a member of the Center for 2-Dimensional and Layered Materials in Penn State's Materials Research Institute.

Story Source:

Materials provided by Penn State Materials Research Institute. Original written by Walt Mills. Note: Content may be edited for style and length.

Journal Reference:

  1. Zhu et al. Gate-controlled topological conducting channels in bilayer graphene. Nature Nanotechnology, 2016 DOI: 10.1038/nnano.2016.158

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Penn State Materials Research Institute. "A device to control 'color' of electrons in graphene provides path to future electronics." ScienceDaily. ScienceDaily, 29 August 2016. <>.
Penn State Materials Research Institute. (2016, August 29). A device to control 'color' of electrons in graphene provides path to future electronics. ScienceDaily. Retrieved May 25, 2017 from
Penn State Materials Research Institute. "A device to control 'color' of electrons in graphene provides path to future electronics." ScienceDaily. (accessed May 25, 2017).