First observation of electronic structure in Ag-Rh alloy nanoparticles having hydrogen absorbing/storage property

In the periodic table of elements, Pd is located between Rh and Ag, two elements incapable of absorbing/storage hydrogen. Bulk Ag and Rh are unable to form alloys. Only when these elements are arranged to be about 10 to 20 nanometers in size, they are capable of forming alloys, and Ag0.5Rh0.5 alloy nanoparticles with a 1-to-1 Ag-Rh content ratio store hydrogen like Pd does. However, it had been unknown why Ag0.5Rh0.5 alloy nanoparticles possessed such an unexpected property. It is critical, in terms of gaining fundamental knowledge in material development, to experimentally and theoretically understand the electronic structure of Ag-Rh alloy nanoparticles, which is believed to be closely associated with the hydrogen absorbing/storage property.

The research team examined the electronic structure of the valence band in Ag-Rh alloy nanoparticles by taking measurements using high resolution photoelectron spectroscopy that emits high-brilliant synchrotron radiation and by conducting theoretical calculations. It is extremely difficult to examine the internal electronic structure of the particles that are about 10 to 20 nanometers in diameter by taking measurements in the laboratory equipped with photoelectron spectroscopy that emits (soft) X-rays with low energy. Therefore, we used (hard) X-rays at the NIMS's beamline housed in the world's largest synchrotron radiation facility (SPring-8). In addition, we accurately interpreted the results of the experiment based on calculated spectra which is proportional in electron density of states. Consequently, we found that Ag-Rh alloy nanoparticles are not merely a mixture of Ag and Rh at a microscopic level, but are a merging of the two elements at the atomic level, and that their electronic structure is nearly identical to that of Pd. The fact that Ag-Rh alloy nanoparticles absorb hydrogen appears to be related to the similarity in electronic structure between the Ag-Rh alloy and Pd.

These results indicate that Ag-Rh alloy nanoparticles are not only capable of absorbing/storage hydrogen due to their electronic structure, but they also may serve as a useful catalyst. In the future, we are planning to advance joint research on characteristics and physical properties of the material. In addition, we intend to provide data on electronic structures and atomic arrangements to industries so that they can take advantage of various new functional materials to be developed besides Ag-Rh alloy nanoparticles. Furthermore, we will establish a foundation to carry out research on design-based materials using proper data (materials informatics).

This research was supported by the Nanotechnology Platform Project sponsored by the Ministry of Education, Culture, Sports, Science and Technology, and the research project titled, "The creation of innovative functions of intelligent materials on the basis of element strategy."