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Benchmarking electrocatalysts for solar water-splitting devices

Date:
June 16, 2015
Source:
Department of Energy, Office of Science
Summary:
Efficiently turning sunlight into storable fuels requires catalysts that convert a maximum amount of solar energy into fuel. A lack of standardized analytic conditions and methods has made objectively comparing catalysts challenging. Scientists standardized measurement techniques to allow a quantitative, objective evaluation of such catalysts.
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Dr. Charles McCrory is setting up a rotating disk electrode experiment, which is used to measure a material’s catalytic activity and stability under conditions that are required for a working water-splitting device. These measurements follow a separate procedure in which the sample’s surface composition is characterized by X-ray photoelectron spectroscopy.
Credit: Image courtesy of Department of Energy, Office of Science

Turning sunlight into storable fuels efficiently requires stable Earth-abundant catalysts that efficiently convert a maximum amount of the solar energy into fuel. Previous studies have described a range of catalysts, but a lack of standardized analytic conditions and methods has made objectively comparing catalysts challenging. Researchers standardized measurement techniques to allow a quantitative, objective evaluation of the activity and stability of water-splitting catalysts.

This study fulfills a longstanding need for unbiased comparison of heterogeneous catalysts' performance in electrochemical water-splitting research and helps inform the development of new artificial photosynthesis device components.

Researchers at the Joint Center for Artificial Photosynthesis (JCAP) have developed uniform benchmarking protocols and have used them to make "apples-to-apples" comparisons of the performance of more than forty catalysts for the evolution of hydrogen fuel and oxygen from water. Researchers evaluated the efficiency of each heterogeneous catalyst, measured as the amount of excess energy that would be required to create fuel in an artificial photosynthetic device operating about ten to a hundred times more efficiently than natural photosynthesis that occurs in crop plants. Researchers also determined the catalyst's stability under laboratory testing conditions.

While the study confirmed the efficiency of many known catalysts, few of the Earth-abundant catalysts for making hydrogen and oxygen from water proved sufficiently active and stable in the conditions that are required for a practical solar fuels generating system, highlighting a priority for future research.


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Materials provided by Department of Energy, Office of Science. Note: Content may be edited for style and length.


Journal Reference:

  1. Charles C. L. McCrory, Suho Jung, Ivonne M. Ferrer, Shawn M. Chatman, Jonas C. Peters, Thomas F. Jaramillo. Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices. Journal of the American Chemical Society, 2015; 137 (13): 4347 DOI: 10.1021/ja510442p

Cite This Page:

Department of Energy, Office of Science. "Benchmarking electrocatalysts for solar water-splitting devices." ScienceDaily. ScienceDaily, 16 June 2015. <www.sciencedaily.com/releases/2015/06/150616093400.htm>.
Department of Energy, Office of Science. (2015, June 16). Benchmarking electrocatalysts for solar water-splitting devices. ScienceDaily. Retrieved May 24, 2017 from www.sciencedaily.com/releases/2015/06/150616093400.htm
Department of Energy, Office of Science. "Benchmarking electrocatalysts for solar water-splitting devices." ScienceDaily. www.sciencedaily.com/releases/2015/06/150616093400.htm (accessed May 24, 2017).

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