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Reconfigurable building blocks for the construction of photonic devices

Date:
March 16, 2016
Source:
Korea Advanced Institute of Science and Technology
Summary:
Photonic microcapsules confining cholesteric liquid crystals are microfluidically produced, potentially serving as building blocks to compose any shapes of photonic devices.
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Reconfigurable building blocks for the construction of photonic devices.
Credit: Copyright KAIST

Photonic microcapsules confining cholesteric liquid crystals are microfluidically produced, potentially serving as building blocks to compose any shapes of photonic devices.

Liquid crystal (LC) molecules spontaneously form helical structures in the presence of chiral molecules, and these structures are referred to as cholesteric LC (CLC). The CLCs exhibit pronounced colors when the helical pitch is comparable with the wavelength of visible light. Such a photonic effect renders the CLCs promising for various photonic devices. Nevertheless, the fluidity of LCs severely limits the ease of processing and structural stability, restricting their applications.

To overcome this limitation, Prof. Shin-Hyun Kim's group at Korea Advanced Institute of Science and Technology (KAIST) has encapsulated the LCs with an elastic membrane. A droplet of LCs is enclosed in another droplet of elastomer precursors using a microfluidic technology. Such a drop-in-drop structure, called a double-emulsion drop, yields stable microcapsule as the precursors are polymerized. The microcapsules containing LCs can serve as building blocks that are assembled to construct any shapes of photonic devices. However, LC molecules in direct contact with the elastomer lose their planar alignment, which severely deteriorates optical performance.

To align the LC molecules at the boundary, an ultra-thin layer is inserted between the LC core and precursor shell. To fulfill this, triple-emulsion drops, composed of an LC core, aqueous inner shell, and precursor outer shell, are produced with a specially-designed microfluidic device. The aqueous inner shell makes the LC molecules have planar alignment at the boundary, resulting in striking colors with high reflectivity. Moreover, the thinness of the alignment layer provides a high lubrication resistance, preserving the layer integrity during elastic deformation of the outer membrane. Therefore, the microcapsules can maintain planar alignment of CLCs, even during microcapsule deformation.

The elastic deformation of microcapsules and adaptive molecular orientation provide high reconfigurability as well as flexible shapes to present various optical features. This class of photonic ink capsules has great potential as new building blocks for the construction of photonic devices. For example, the microcapsules can be densely packed to form void-free panels with any shapes. More importantly, spontaneous rearrangement of CLC molecules guided by an alignment layer in each deformed microcapsule can maximize the reflection intensity of the panels.


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Materials provided by Korea Advanced Institute of Science and Technology. Note: Content may be edited for style and length.


Journal Reference:

  1. Sang Seok Lee, Su Kyung Kim, Jong Chan Won, Yun Ho Kim, Shin-Hyun Kim. Reconfigurable Photonic Capsules Containing Cholesteric Liquid Crystals with Planar Alignment. Angewandte Chemie International Edition, 2015; 54 (50): 15266 DOI: 10.1002/anie.201507723

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Korea Advanced Institute of Science and Technology. "Reconfigurable building blocks for the construction of photonic devices." ScienceDaily. ScienceDaily, 16 March 2016. <www.sciencedaily.com/releases/2016/03/160316140637.htm>.
Korea Advanced Institute of Science and Technology. (2016, March 16). Reconfigurable building blocks for the construction of photonic devices. ScienceDaily. Retrieved May 23, 2017 from www.sciencedaily.com/releases/2016/03/160316140637.htm
Korea Advanced Institute of Science and Technology. "Reconfigurable building blocks for the construction of photonic devices." ScienceDaily. www.sciencedaily.com/releases/2016/03/160316140637.htm (accessed May 23, 2017).

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