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Boron boosts graphene's sensitivity to noxious gases

Date:
July 29, 2016
Source:
Department of Energy, Office of Science
Summary:
Researchers have discovered a way to significantly improve graphene's performance in detecting noxious gases. They peppered high-quality sheets with boron impurities.
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Experimental observations (left) confirm theory-based simulations (right) of boron-doped graphene. Boomerang-shaped atomic features revealed in a centimeter-wide sheet of boron-doped graphene are associated with enhanced sensitivities for nitrogen dioxide and ammonia detection.
Credit: Reprinted from: R. Lv, “Ultrasensitive Gas Detection of Large-area Boron-doped Graphene.” PNAS 112 (47), 14527–14532 (2015). DOI: 10.1073/pnas.1505993112. Copyright 2015 Proceedings of the National Academy of Sciences USA

Detecting noxious gases, such as those released from power plants and other sources that can harm the environment, is something graphene does well, but it could be even better. Researchers discovered a way to significantly improve its performance by peppering high-quality graphene sheets with boron impurities. Compared to pristine graphene, these modified sheets, a.k.a. boron-doped graphene, were 27 times more sensitive at detecting nitrogen dioxide and 105 times more sensitive at detecting ammonia.

Ultrasensitive gas detectors based on this proof-of-principle experiment could monitor environmental health and safety. Sheets of doped graphene with useful electronic and magnetic properties could also find application in field-effect transistors, hydrogen storage, and lithium-ion batteries.

Theory predicts that graphene could be much better at detecting noxious gases if impurities, or dopants, were incorporated into its rigid framework of one-atom-thick carbon. Experimental progress, however, has been limited by a lack of high-quality boron-doped graphene. Here, scientists grew highly ordered, centimeter-wide sheets of boron-doped graphene and observed, for the first time, boomerang-shaped features corresponding to dopant atoms embedded within graphene's hexagonal matrix. They characterized the material's electronic properties, which depend on how impurity atoms incorporate into graphene's honeycomb lattice and create defects that change the way gases chemically interact with graphene, which in turn alters current flow. To discover the atomic-level details of how boron doping changes graphene's properties, the researchers went to the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility at Oak Ridge National Laboratory, for advanced instrumentation and expertise in low-voltage electron microscopy and scanning tunneling microscopy. Results showed that, compared with pristine graphene, boron doping increases the gas sensing capability of graphene to parts per billion for nitrogen dioxide and parts per million for ammonia.


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Journal Reference:

  1. Ruitao Lv, Gugang Chen, Qing Li, Amber McCreary, Andrés Botello-Méndez, S. V. Morozov, Liangbo Liang, Xavier Declerck, Nestor Perea-López, David A. Cullen, Simin Feng, Ana Laura Elías, Rodolfo Cruz-Silva, Kazunori Fujisawa, Morinobu Endo, Feiyu Kang, Jean-Christophe Charlier, Vincent Meunier, Minghu Pan, Avetik R. Harutyunyan, Konstantin S. Novoselov, Mauricio Terrones. Ultrasensitive gas detection of large-area boron-doped graphene. Proceedings of the National Academy of Sciences, 2015; 112 (47): 14527 DOI: 10.1073/pnas.1505993112

Cite This Page:

Department of Energy, Office of Science. "Boron boosts graphene's sensitivity to noxious gases." ScienceDaily. ScienceDaily, 29 July 2016. <www.sciencedaily.com/releases/2016/07/160729152118.htm>.
Department of Energy, Office of Science. (2016, July 29). Boron boosts graphene's sensitivity to noxious gases. ScienceDaily. Retrieved May 24, 2017 from www.sciencedaily.com/releases/2016/07/160729152118.htm
Department of Energy, Office of Science. "Boron boosts graphene's sensitivity to noxious gases." ScienceDaily. www.sciencedaily.com/releases/2016/07/160729152118.htm (accessed May 24, 2017).

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