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When nuclei catch up with electrons

April 16, 2018
ETH Zurich Department of Physics
In an attosecond study of the H2 molecule physicists found that for light atomic nuclei -- as contained in most organic and biological molecules -- the correlation between electronic and nuclear motions cannot be ignored.

Understanding the dynamics of quantum-mechanical systems on their natural time scale is the main goal in attosecond science. Among the most interesting systems to investigate are molecules, which have a very high degree of complexity, in particular when compared to atomic systems. So far, the few attosecond experiments performed on molecules have provided valuable insight into electron dynamics. In these studies, the dynamics of the nuclei around which the electrons evolve was assumed to be 'frozen', given that nuclei are much heavier than electrons and therefore move more slowly. However, even in the attosecond time regime, the approximation that electronic and nuclear motion are decoupled from one another is often not justified. In particular in molecules composed of light atomic species, the nuclear motion can be as fast as electron dynamics, resulting in a strong coupling between the two.

A team led by Dr. Laura Cattaneo and Prof. Ursula Keller in the Department of Physics at ETH Zurich has now studied the lightest and smallest of all molecules, H2, and explored what happens when nuclear and electronic motion happen on a comparable time scale. As they report in an article published today in Nature Physics, they found that in molecules ionization delays -- the time between the absorption of a photon and the emission of an electron during photoionization -- can significantly depend on the kinetic energy of both the photoelectron and the nuclei. This finding extends the concept of ionization delays introduced for atomic systems. Variations of ionization delays with the nuclear kinetic energy can be as large as variations with the electronic kinetic energy. This implies that whenever light atoms are involved in the molecular ionization process, the outgoing electron wave packet cannot be disentangled from the nuclear wave packet.

These measurements at the attosecond time scale are based on an experimental approach developed earlier in the Keller group. In the so-called AttoCOLTRIMS apparatus attosecond metrology is combined with the imaging technique COLTRIMS, in which the correlated properties of the fragments of a molecular reaction can be recorded. This experimental capability was combined with nearly exact ab initio theory, performed by collaborators at the Universidad Autonoma de Madrid (Spain), to describe both electronic and nuclear motions, as well the coupling between them.

The significance of this work goes well beyond the simple H2 molecule studied. Hydrogen atoms are present in most organic and biologically relevant molecules. Understanding the effects and contributions from coupled electron and nuclear dynamics present in such systems should therefore provide fundamental insight that will be important in various fields of research.

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Materials provided by ETH Zurich Department of Physics. Note: Content may be edited for style and length.

Journal Reference:

  1. L. Cattaneo, J. Vos, R. Y. Bello, A. Palacios, S. Heuser, L. Pedrelli, M. Lucchini, C. Cirelli, F. Martín, U. Keller. Attosecond coupled electron and nuclear dynamics in dissociative ionization of H2. Nature Physics, 2018; DOI: 10.1038/s41567-018-0103-2

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ETH Zurich Department of Physics. "When nuclei catch up with electrons." ScienceDaily. ScienceDaily, 16 April 2018. <>.
ETH Zurich Department of Physics. (2018, April 16). When nuclei catch up with electrons. ScienceDaily. Retrieved April 19, 2024 from
ETH Zurich Department of Physics. "When nuclei catch up with electrons." ScienceDaily. (accessed April 19, 2024).

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