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Highly efficient and stable double layer solar cell developed

Date:
March 27, 2020
Source:
The Korea Advanced Institute of Science and Technology (KAIST)
Summary:
A research team has developed a new type of solar cell that can both withstand environmental hazards and is 26.7% efficient in power conversion.
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Solar cells convert light into energy, but they can be inefficient and vulnerable to the environment, degrading with, ironically, too much light or other factors, including moisture and low temperature. An international research team has developed a new type of solar cell that can both withstand environmental hazards and is 26.7% efficient in power conversion.

They published their results on March 26 in Science.

The researchers, led by Byungha Shin, a professor from the Department of Materials Science and Engineering at KAIST, focused on developing a new class of light-absorbing material, called a wide bandgap perovskite. The material has a highly effective crystal structure that can process the power needs, but it can become problematic when exposed to environmental hazards, such as moisture. Researchers have made some progress increasing the efficiency of solar cells based on perovskite, but the material has greater potential than what was previously achieved.

To achieve better performance, Shin and his team built a double layer solar cell, called tandem, in which two or more light absorbers are stacked together to better utilize solar energy. To use perovskite in these tandem devices, the scientists modified the material's optical property, which allows it to absorb a wider range of solar energy. Without the adjustment, the material is not as useful in achieving high performing tandem solar cells. The modification of the optical property of perovskite, however, comes with a penalty -- the material becomes hugely vulnerable to the environment, in particular, to light.

To counteract the wide bandgap perovskite's delicate nature, the researchers engineered combinations of molecules composing a two-dimensional layer in the perovskite, stabilizing the solar cells.

"We developed a high-quality wide bandgap perovskite material and, in combination with silicon solar cells, achieved world-class perovskite-silicon tandem cells," Shin said.

The development was only possible due to the engineering method, in which the mixing ratio of the molecules building the two-dimensional layer are carefully controlled. In this case, the perovskite material not only improved efficiency of the resulting solar cell but also gained durability, retaining 80% of its initial power conversion capability even after 1,000 hours of continuous illumination. This is the first time such a high efficiency has been achieved with a wide bandgap perovskite single layer alone, according to Shin.

"Such high-efficiency wide bandgap perovskite is an essential technology for achieving ultra-high efficiency of perovskite-silicon tandem (double layer) solar cells," Shin said. "The results also show the importance of bandgap matching of upper and lower cells in these tandem solar cells."

The researchers, having stabilized the wide bandgap perovskite material, are now focused on developing even more efficient tandem solar cells that are expected to have more than 30% of power conversion efficiency, something that no one has achieved yet,

"Our ultimate goal is to develop ultra-high-efficiency tandem solar cells that contribute to the increase of shared solar energy among all energy sources," Shin said. "We want to contribute to making the planet healthier."


Story Source:

Materials provided by The Korea Advanced Institute of Science and Technology (KAIST). Note: Content may be edited for style and length.


Journal Reference:

  1. Daehan Kim, Hee Joon Jung, Ik Jae Park, Bryon W. Larson, Sean P. Dunfield, Chuanxiao Xiao, Jekyung Kim, Jinhui Tong, Passarut Boonmongkolras, Su Geun Ji, Fei Zhang, Seong Ryul Pae, Minkyu Kim, Seok Beom Kang, Vinayak Dravid, Joseph J. Berry, Jin Young Kim, Kai Zhu, Dong Hoe Kim, Byungha Shin. Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites. Science, 2020; eaba3433 DOI: 10.1126/science.aba3433

Cite This Page:

The Korea Advanced Institute of Science and Technology (KAIST). "Highly efficient and stable double layer solar cell developed." ScienceDaily. ScienceDaily, 27 March 2020. <www.sciencedaily.com/releases/2020/03/200327103038.htm>.
The Korea Advanced Institute of Science and Technology (KAIST). (2020, March 27). Highly efficient and stable double layer solar cell developed. ScienceDaily. Retrieved March 18, 2024 from www.sciencedaily.com/releases/2020/03/200327103038.htm
The Korea Advanced Institute of Science and Technology (KAIST). "Highly efficient and stable double layer solar cell developed." ScienceDaily. www.sciencedaily.com/releases/2020/03/200327103038.htm (accessed March 18, 2024).

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