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Greener solution powers new method for lithium-ion battery recycling

Date:
November 29, 2023
Source:
DOE/Oak Ridge National Laboratory
Summary:
Used lithium-ion batteries from cell phones, laptops and a growing number of electric vehicles are piling up, but options for recycling them remain limited mostly to burning or chemically dissolving shredded batteries. Researchers have improved on approaches that dissolve the battery in a liquid solution in order to reduce the amount of hazardous chemicals used in the process. This simple, efficient and environmentally-friendly solution overcomes the main obstacles presented by previous approaches.
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Used lithium-ion batteries from cell phones, laptops and a growing number of electric vehicles are piling up, but options for recycling them remain limited mostly to burning or chemically dissolving shredded batteries. The current state of the art methods can pose environmental challenges and be difficult to make economical at the industrial scale.

The conventional process recovers few of the battery materials and relies on caustic, inorganic acids and hazardous chemicals that may introduce impurities. It also requires complicated separation and precipitation to recover the critical metals. However, recovering metals such as cobalt and lithium could reduce both pollution and reliance on foreign sources and choked supply chains.

Researchers at the Department of Energy's Oak Ridge National Laboratory have improved on approaches that dissolve the battery in a liquid solution in order to reduce the amount of hazardous chemicals used in the process.

This simple, efficient and environmentally-friendly solution developed by ORNL researchers overcomes the main obstacles presented by previous approaches.

The spent battery is soaked in a solution of organic citric acid -- which occurs naturally in citrus fruits -- dissolved in ethylene glycol, an antifreeze agent commonly used in consumer products like paint and makeup. Citric acid comes from sustainable sources and is much safer to handle than inorganic acids. This green solution produced a strikingly efficient separation and recovery process for the metals from the positively-charged electrode of the battery, called the cathode.

"Because the cathode contains the critical materials, it is the most expensive part of any battery, contributing more than 30% of the cost," said Yaocai Bai, a member of the ORNL battery research team. "Our approach could reduce the cost of batteries over time." The research was conducted in ORNL's Battery Manufacturing Facility, the country's largest open-access battery manufacturing research and development center.

The recycling technique developed there leached nearly 100% of the cobalt and lithium from the cathode without introducing impurities in the system. It also enabled efficient separation of the metal solution from other residues. Most importantly, it served a second function by recovering over 96% of the cobalt in a matter of hours, without the typical addition of more chemicals in what is usually a tricky process of manually balancing acid levels.

"This is the first time one solution system has covered the functions of both leaching and recovery," said lead researcher Lu Yu. "It was exciting to find that the cobalt would precipitate and settle out without further interference. We were not expecting that."

Eliminating the need for extra chemicals reduces costs and avoids creating byproducts or secondary wastes. "We are glad this recycling process developed by our scientists can pave the way for greater recovery of battery critical materials," said Ilias Belharouak, corporate fellow and head of the ORNL's electrification section.

The leaching performance of citric acid and ethylene glycol has been explored before, but that approach used more acid and a lower temperature, which proved less effective, Bai said.

"We were surprised by how quickly the leaching happened in our solution," Bai said. "With an organic acid, it usually takes 10-12 hours, but this took only one." Conventional solutions using inorganic acid are also slower because they include water, which has a boiling point that limits the temperature of the reaction.


Story Source:

Materials provided by DOE/Oak Ridge National Laboratory. Note: Content may be edited for style and length.


Journal Reference:

  1. Lu Yu, Yaocai Bai, Rachid Essehli, Anuj Bisht, Ilias Belharouak. Efficient separation and coprecipitation for simplified cathode recycling. Energy Storage Materials, 2023; 63: 103025 DOI: 10.1016/j.ensm.2023.103025

Cite This Page:

DOE/Oak Ridge National Laboratory. "Greener solution powers new method for lithium-ion battery recycling." ScienceDaily. ScienceDaily, 29 November 2023. <www.sciencedaily.com/releases/2023/11/231129112422.htm>.
DOE/Oak Ridge National Laboratory. (2023, November 29). Greener solution powers new method for lithium-ion battery recycling. ScienceDaily. Retrieved February 22, 2024 from www.sciencedaily.com/releases/2023/11/231129112422.htm
DOE/Oak Ridge National Laboratory. "Greener solution powers new method for lithium-ion battery recycling." ScienceDaily. www.sciencedaily.com/releases/2023/11/231129112422.htm (accessed February 22, 2024).

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