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Making quantum 'waves' in ultrathin materials

Study reveals how wavelike plasmons could power up a new class of sensing and photochemical technologies at the nanoscale

Date:
May 14, 2020
Source:
DOE/Lawrence Berkeley National Laboratory
Summary:
A team of researchers has observed unusually long-lived wavelike electrons called 'plasmons' in a new class of electronically conducting material. Plasmons are very important for determining the optical and electronic properties of metals for the development of new sensors and communication devices.
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Wavelike, collective oscillations of electrons known as "plasmons" are very important for determining the optical and electronic properties of metals.

In atomically thin 2D materials, plasmons have an energy that is more useful for applications, including sensors and communication devices, than plasmons found in bulk metals. But determining how long plasmons live and whether their energy and other properties can be controlled at the nanoscale (billionths of a meter) has eluded many.

Now, as reported in the journal Nature Communications, a team of researchers co-led by the Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) -- with support from the Department of Energy's Center for Computational Study of Excited-State Phenomena in Energy Materials (C2SEPEM) -- has observed long-lived plasmons in a new class of conducting transition metal dichalcogenide (TMD) called "quasi 2D crystals."

To understand how plasmons operate in quasi 2D crystals, the researchers characterized the properties of both nonconductive electrons as well as conductive electrons in a monolayer of the TMD tantalum disulfide. Previous studies only looked at conducting electrons. "We discovered that it was very important to carefully include all the interactions between both types of electrons," said C2SEPEM Director Steven Louie, who led the study. Louie also holds titles as senior faculty scientist in the Materials Sciences Division at Berkeley Lab and professor of physics at UC Berkeley.

The researchers developed sophisticated new algorithms to compute the material's electronic properties, including plasmon oscillations with long wavelengths, "as this was a bottleneck with previous computational approaches," said lead author Felipe da Jornada, who was a postdoctoral researcher in Berkeley Lab's Materials Sciences Division at the time of the study. Jornada is currently an assistant professor in materials science and engineering at Stanford University.

To the researchers' surprise, the results from calculations performed by the Cori supercomputer at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC) revealed that plasmons in quasi 2D TMDs are much more stable -- for as long as approximately 2 picoseconds, or 2 trillionths of a second -- than previously thought.

Their findings also suggest that plasmons generated by quasi 2D TMDs could enhance the intensity of light by more than 10 million times, opening the door for renewable chemistry (chemical reactions triggered by light), or the engineering of electronic materials that can be controlled by light.

In future studies, the researchers plan to investigate how to harness the highly energetic electrons released by such plasmons upon decay, and if they can be used to catalyze chemical reactions.


Story Source:

Materials provided by DOE/Lawrence Berkeley National Laboratory. Note: Content may be edited for style and length.


Journal Reference:

  1. Felipe H. da Jornada, Lede Xian, Angel Rubio, Steven G. Louie. Universal slow plasmons and giant field enhancement in atomically thin quasi-two-dimensional metals. Nature Communications, 2020; 11 (1) DOI: 10.1038/s41467-020-14826-8

Cite This Page:

DOE/Lawrence Berkeley National Laboratory. "Making quantum 'waves' in ultrathin materials." ScienceDaily. ScienceDaily, 14 May 2020. <www.sciencedaily.com/releases/2020/05/200514131735.htm>.
DOE/Lawrence Berkeley National Laboratory. (2020, May 14). Making quantum 'waves' in ultrathin materials. ScienceDaily. Retrieved March 27, 2024 from www.sciencedaily.com/releases/2020/05/200514131735.htm
DOE/Lawrence Berkeley National Laboratory. "Making quantum 'waves' in ultrathin materials." ScienceDaily. www.sciencedaily.com/releases/2020/05/200514131735.htm (accessed March 27, 2024).

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