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Breaking down BPA and similar pollutants with sunlight, nanoparticles and graphene

Date:
November 5, 2014
Source:
American Chemical Society
Summary:
Many pollutants with the potential to meddle with hormones -- with bisphenol A, better known as BPA, as a prime example -- are already common in the environment. In an effort to clean up these pollutants found in the soil and waterways, scientists are now reporting a novel way to break them down by recruiting help from nanoparticles and light.
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Many pollutants with the potential to meddle with hormones -- with bisphenol A (BPA) as a prime example -- are already common in the environment. In an effort to clean up these pollutants found in the soil and waterways, scientists are now reporting a novel way to break them down by recruiting help from nanoparticles and light. The study appears in the journal ACS Applied Materials & Interfaces.

Nikhil R. Jana and Susanta Kumar Bhunia explain that the class of pollutants known as endocrine disruptors has been shown to either mimic or block hormones in animals, including humans. That interference can cause reproductive and other health problems. The compounds are used to make many household and industrial products, and have been detected in soil, water and even human breast milk. Scientists have been working on ways to harness sunlight to break down endocrine disruptors to make them less of a health threat. But the approaches so far only work with ultraviolet light, which at a mere 6 percent of sunlight, means these methods are not very efficient. Jana and Bhunia wanted to find a simple way to take advantage of visible light, which comprises 52 percent of sunlight.

For inspiration, the researchers turned to an already-developed graphene composite that uses visible light to degrade dyes. They tweaked the composite and loaded it with silver nanoparticles that serve as an antenna for visible light. When they tested it, the new material successfully degraded three different kinds of endocrine disruptors: phenol, BPA and atrazine. They conclude that their composite is a promising way to harness visible light to break down these potentially harmful compounds and other organic pollutants.


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Materials provided by American Chemical Society. Note: Content may be edited for style and length.


Journal Reference:

  1. Susanta Kumar Bhunia, Nikhil R. Jana. Reduced Graphene Oxide-Silver Nanoparticle Composite as Visible Light Photocatalyst for Degradation of Colorless Endocrine Disruptors. ACS Applied Materials & Interfaces, 2014; 141021083321007 DOI: 10.1021/am505677x

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American Chemical Society. "Breaking down BPA and similar pollutants with sunlight, nanoparticles and graphene." ScienceDaily. ScienceDaily, 5 November 2014. <www.sciencedaily.com/releases/2014/11/141105101303.htm>.
American Chemical Society. (2014, November 5). Breaking down BPA and similar pollutants with sunlight, nanoparticles and graphene. ScienceDaily. Retrieved April 19, 2024 from www.sciencedaily.com/releases/2014/11/141105101303.htm
American Chemical Society. "Breaking down BPA and similar pollutants with sunlight, nanoparticles and graphene." ScienceDaily. www.sciencedaily.com/releases/2014/11/141105101303.htm (accessed April 19, 2024).

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