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Research pinpoints promise of polycrystalline perovskites

Date:
February 7, 2017
Source:
DOE/National Renewable Energy Laboratory
Summary:
A team of scientists has determined that surface recombination limits the performance of polycrystalline perovskite solar cells.
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A team of scientists from the Energy Department's National Renewable Energy Laboratory (NREL) determined that surface recombination limits the performance of polycrystalline perovskite solar cells.

Considerable research into perovskites at NREL and elsewhere has proved the material's effectiveness at converting sunlight into electricity, routinely topping 20 percent efficiency. The sunlight creates mobile electrons whose movement generates the power but upon encountering defects can slip into a non-productive process. Known as a recombination, this process reduces the efficiency of a solar cell. For the cell to be the most efficient, the recombination must occur slowly.

With prior studies into perovskites focusing on bulk recombination, one area left unexamined until now concerned the surface recombination in lead iodide perovskites. NREL's scientists determined recombination in other parts of a methylammonium perovskite film isn't as important as what's happening on the surface, both the top and bottom.

Matthew Beard and his colleagues within NREL's Chemistry and Nanoscience Center studied surface recombination in single-crystal and polycrystalline films using transient reflection spectroscopy. Their findings, Top and bottom surfaces limit carrier lifetime in lead iodide perovskite films, appear in Nature Energy.

"What's important is to know where the recombination is coming from," said Beard, lead author of the research paper. "There are multiple sources of possible recombination. In order to improve your device, you're asked to get rid of all non-radiative recombination. Typically people forget about surfaces. They think about grain boundaries. They think about bulk defects and so forth."

Beard's co-authors are all from NREL: Ye Yang, Mengjin Yang, David T. Moore, Yong Yan, Elisa M. Miller, and Kai Zhu.

Beard said the research determined surface recombination emerged as an obstacle to overcome. Surface recombination directly affects the performance of a photovoltaic device. The ability to engineer surfaces stands poised to benefit perovskite-based optoelectronic applications. A fast surface recombination can be used to design photodetectors, while lasers and light-emitting diodes require a slower speed.

A second study that concurrently appeared in the journal Physical Chemistry Chemical Physics was authored by Mengjin Yang, Yining Zeng, Zhen Li, DongHoe Kim, Chun-Sheng Jiang, Jao van de Lagemaat, and Kai Zhu further strengthened the conclusions of the paper. This study, using high-resolution fluorescence-lifetime imaging, also showed that surface recombination is the determining factor instead of grain boundary recombination.

The researchers compared two types of samples: single crystals and polycrystalline films. Surprisingly surface recombination is worse for single crystalline samples compared to the polycrystalline samples found in solar cell devices. Chemically, excess methylammonium iodide was present on the surface of the polycrystalline film but absent on the single-crystal sample.

"That seems to help," Beard said. "The single crystal has a lead-rich surface and a faster surface recombination."

The research suggested a light coating of a protective material on the surface of the polycrystalline thin films could further improve the performance of perovskite solar cells.


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Materials provided by DOE/National Renewable Energy Laboratory. Note: Content may be edited for style and length.


Journal References:

  1. Ye Yang, Mengjin Yang, David T. Moore, Yong Yan, Elisa M. Miller, Kai Zhu, Matthew C. Beard. Top and bottom surfaces limit carrier lifetime in lead iodide perovskite films. Nature Energy, 2017; 2: 16207 DOI: 10.1038/nenergy.2016.207
  2. Mengjin Yang, Yining Zeng, Zhen Li, Dong Hoe Kim, Chun-Sheng Jiang, Jao van de Lagemaat, Kai Zhu. Do grain boundaries dominate non-radiative recombination in CH3NH3PbI3 perovskite thin films? Phys. Chem. Chem. Phys., 2017; DOI: 10.1039/C6CP08770A

Cite This Page:

DOE/National Renewable Energy Laboratory. "Research pinpoints promise of polycrystalline perovskites." ScienceDaily. ScienceDaily, 7 February 2017. <www.sciencedaily.com/releases/2017/02/170207142653.htm>.
DOE/National Renewable Energy Laboratory. (2017, February 7). Research pinpoints promise of polycrystalline perovskites. ScienceDaily. Retrieved May 23, 2017 from www.sciencedaily.com/releases/2017/02/170207142653.htm
DOE/National Renewable Energy Laboratory. "Research pinpoints promise of polycrystalline perovskites." ScienceDaily. www.sciencedaily.com/releases/2017/02/170207142653.htm (accessed May 23, 2017).

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