Fireworks displays can cause health problems, such as respiratory ailments, because they release high levels of air pollutants, including particulate matter (PM), sulfur dioxide, heavy metals and perchlorates. As a result, some cities have banned their use. But because the displays are an important aspect of many traditional celebrations, researchers and manufacturers have tried to develop more environmentally friendly pyrotechnics, including those with smokeless charges and sulfur-free propellants. Although research suggests that these fireworks emit less pollutants, their impact on air quality has not been evaluated. Ying Li and colleagues wanted to use data from a large fireworks display held in Shenzhen, China, on Chinese National Day on Oct. 1, 2019, to assess how "green" these fireworks really are.

The researchers estimated emissions of PM_2.5, which is PM with a diameter of 2.5 ?m and smaller, from the 160,000 environmentally friendly fireworks set off during the display, as well as emissions from traditional fireworks. They used information on the wind direction, wind speed, temperature and chemical composition of the fireworks to simulate the size, trajectory and peak PM_2.5 values for the smoke plume resulting from the event. Then, they compared their simulated values with actual data on PM_2.5 concentrations measured at 75 monitoring stations throughout the city following the fireworks display. In agreement with the team's predictions, the data showed that the fireworks smoke plume began as a narrow band that traveled northward before being fully dispersed, with peak PM_2.5 levels similar to the predictions. The researchers used their validated simulation to estimate that the use of environmentally friendly fireworks produces a much smaller, shorter-lasting plume, with 15-65% of the PM_2.5 emissions of a display using traditional fireworks. However, the peak concentration of PM_2.5 still greatly exceeds World Health Organization guidelines. This led the researchers to conclude that the number of "green" fireworks used at one time should be restricted.

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Materials provided by American Chemical Society. Note: Content may be edited for style and length.

Journal Reference:

1. Shidong Fan, Ying Li, Chanfang Liu. Are Environmentally Friendly Fireworks Really “Green” for Air Quality? A Study from the 2019 National Day Fireworks Display in Shenzhen. Environmental Science & Technology, 2021; DOI: 10.1021/acs.est.0c03521