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New ionic materials boost hydrogen fuel cell efficiency!

Their findings have been selected for the back cover of Angew. Chem. Int. Ed. and published on June 20, 2023

Date:
September 11, 2023
Source:
Ulsan National Institute of Science and Technology(UNIST)
Summary:
A research team has made a groundbreaking advancement in improving the efficiency of hydrogen fuel cells, which are gaining significant attention as eco-friendly next-generation energy sources.
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A team of researchers, affiliated with UNIST has made a groundbreaking advancement in improving the efficiency of hydrogen fuel cells, which are gaining significant attention as eco-friendly next-generation energy sources.

Led by Professor Myoung Soo Lah in the Department of Chemistry at UNIST, the team successfully developed solid electrolyte materials utilizing metal-organic frameworks (MOFs). This innovative approach significantly enhances the conductivity of hydrogen ions within the solid electrolyte employed in hydrogen fuel cells. Furthermore, the research team introduced guest molecules with low acidity -- marking a pioneering achievement among intermediaries used for this purpose. By implementing a novel methodology that increases the number of guest molecules inside MOF pores, they achieved improved hydrogen ion conductivity.

Hydrogen fuel cells are highly efficient and environmentally friendly power generation devices that directly convert chemical energy derived from reactions between hydrogen and oxygen into electrical energy. Currently, Proton-Exchange Membrane Fuel Cells predominantly employ Nafion as an electrolyte material due to its thermal, mechanical, and chemical stability alongside high hydrogen ion conductivity. However, these systems face limitations regarding their operating temperature range and lack clarity on their mechanisms for performance enhancement.

The research team turned their attention to MOFs as potential alternatives. MOFs are materials composed of metal clusters interconnected by organic ligands to form a porous structure. With excellent chemical and thermal stability properties, MOFs have recently garnered considerable interest for use in fuel cell applications. Moreover, when generated, MOFs possess pores of varying sizes that can be utilized for developing materials with high hydrogen ion conductivity by introducing guest molecules through these channels.

In this study conducted by the research team at UNIST led by Professor Myoung Soo Lah's group members , zwitterionic sulfamic acid -- a low-acidity amphoteric ionic substance possessing both positive and negative charges -- was introduced as guest molecules into two types of MOFs, namely MOF-808 and MIL-101. Sulfamic acid, a guest molecule with exceptional hydrogen bonding capabilities in various forms, effectively operates as a medium for transferring hydrogen ions. By increasing the amount of sulfamic acid within the pores of MOFs, the team successfully developed materials demonstrating high hydrogen ion conductivity (achieving levels of 10-1 Scm-1 or higher). Moreover, these materials exhibited remarkable durability as they maintained hydrogen ion conductivity over an extended period.

The research findings hold immense promise for advancing the efficiency and performance of hydrogen fuel cells through the utilization of metal-organic frameworks. This breakthrough contributes to accelerating progress toward sustainable energy solutions in line with global efforts towards decarbonization.

The study findings have been published ahead of their official publication in the online version of Angewandte Chemie International Edition on March 26, 2023. This work was selected for the back cover of the journal and was subsequently published on June 20, 2023.


Story Source:

Materials provided by Ulsan National Institute of Science and Technology(UNIST). Original written by JooHyeon Heo. Note: Content may be edited for style and length.


Journal Reference:

  1. Amitosh Sharma, Jaewoong Lim, Seonghwan Lee, Seungwan Han, Junmo Seong, Seung Bin Baek, Myoung Soo Lah. Superprotonic Conductivity of MOFs Confining Zwitterionic Sulfamic Acid as Proton Source and Conducting Medium. Angewandte Chemie International Edition, 2023; 62 (29) DOI: 10.1002/anie.202302376

Cite This Page:

Ulsan National Institute of Science and Technology(UNIST). "New ionic materials boost hydrogen fuel cell efficiency!." ScienceDaily. ScienceDaily, 11 September 2023. <www.sciencedaily.com/releases/2023/09/230911141159.htm>.
Ulsan National Institute of Science and Technology(UNIST). (2023, September 11). New ionic materials boost hydrogen fuel cell efficiency!. ScienceDaily. Retrieved April 14, 2024 from www.sciencedaily.com/releases/2023/09/230911141159.htm
Ulsan National Institute of Science and Technology(UNIST). "New ionic materials boost hydrogen fuel cell efficiency!." ScienceDaily. www.sciencedaily.com/releases/2023/09/230911141159.htm (accessed April 14, 2024).

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