New! Sign up for our free email newsletter.
Science News
from research organizations

Atmospheric aerosol formation from biogenic vapors is strongly affected by air pollutants

Date:
December 14, 2018
Source:
University of Helsinki
Summary:
According to a recent study, air pollution not only affects air quality, but it also changes the pathways along which new particles are formed in the atmosphere.
Share:
FULL STORY

The formation of new aerosol particles is a complicated process. Researchers have only recently started to understand this process on a molecular level after instruments able to detect nanometer-scale particles became available.

The human population has altered the composition of atmospheric gas in several ways. Sulfur dioxide from industrial emissions, nitrogen oxides from traffic, and ammonia from agriculture can all affect particle formation after chemical reactions in the atmosphere. These gases can also interact with organic vapors, which originate mainly from forests and vegetation. The atmosphere contains thousands of different organic compounds, but only a small fraction of them can form and grow particles.

Earlier it was thought that new particle formation always requires sulfuric acid, which forms from the oxidation of sulfur dioxide. Later, it was found that certain organic vapors can also form particles. In this study, the researchers found that in continental moderately polluted atmospheres, e.g. in the Finnish boreal forest, particles are formed most efficiently when sulfuric acid, ammonia and organic vapors are all present simultaneously. Nitrogen oxides, on the other hand, decreased the amount of newly formed particles.

The results help to understand how new particle formation and the associated climate impact will change if air pollution levels decrease in the future due to stricter emission control. Aerosol particles can affect the climate by scattering solar radiation and by acting as seed particles for cloud droplets. The aerosol-cloud-climate interactions are still associated with large uncertainties in current climate models.

The laboratory experiments leading to these results were conducted at the European Center for Nuclear Research, CERN, in Geneva, which has one of the best laboratory facilities for detailed particle formation studies. The study was led by Associate Professor Katrianne Lehtipalo from the University of Helsinki.

"We wanted to create the boreal forest atmosphere in our chamber," she says. Long-term field measurements at the Hyytiala SMEAR II station in southern Finland helped the researchers to identify the right conditions for particle formation.

"Particle formation is a delicate process, and it took us a while to find the correct gas mixture, but in the end we were able to replicate atmospheric observations almost perfectly," Lehtipalo says.

The study was conducted in collaboration between 25 different institutes in 9 different countries.


Story Source:

Materials provided by University of Helsinki. Note: Content may be edited for style and length.


Journal Reference:

  1. Katrianne Lehtipalo, Chao Yan, Lubna Dada, Federico Bianchi, Mao Xiao, Robert Wagner, Dominik Stolzenburg, Lauri R. Ahonen, Antonio Amorim, Andrea Baccarini, Paulus S. Bauer, Bernhard Baumgartner, Anton Bergen, Anne-Kathrin Bernhammer, Martin Breitenlechner, Sophia Brilke, Angela Buchholz, Stephany Buenrostro Mazon, Dexian Chen, Xuemeng Chen, Antonio Dias, Josef Dommen, Danielle C. Draper, Jonathan Duplissy, Mikael Ehn, Henning Finkenzeller, Lukas Fischer, Carla Frege, Claudia Fuchs, Olga Garmash, Hamish Gordon, Jani Hakala, Xucheng He, Liine Heikkinen, Martin Heinritzi, Johanna C. Helm, Victoria Hofbauer, Christopher R. Hoyle, Tuija Jokinen, Juha Kangasluoma, Veli-Matti Kerminen, Changhyuk Kim, Jasper Kirkby, Jenni Kontkanen, Andreas Kürten, Michael J. Lawler, Huajun Mai, Serge Mathot, Roy L. Mauldin, Ugo Molteni, Leonid Nichman, Wei Nie, Tuomo Nieminen, Andrea Ojdanic, Antti Onnela, Monica Passananti, Tuukka Petäjä, Felix Piel, Veronika Pospisilova, Lauriane L. J. Quéléver, Matti P. Rissanen, Clémence Rose, Nina Sarnela, Simon Schallhart, Simone Schuchmann, Kamalika Sengupta, Mario Simon, Mikko Sipilä, Christian Tauber, António Tomé, Jasmin Tröstl, Olli Väisänen, Alexander L. Vogel, Rainer Volkamer, Andrea C. Wagner, Mingyi Wang, Lena Weitz, Daniela Wimmer, Penglin Ye, Arttu Ylisirniö, Qiaozhi Zha, Kenneth S. Carslaw, Joachim Curtius, Neil M. Donahue, Richard C. Flagan, Armin Hansel, Ilona Riipinen, Annele Virtanen, Paul M. Winkler, Urs Baltensperger, Markku Kulmala, Douglas R. Worsnop. Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors. Science Advances, 2018; 4 (12): eaau5363 DOI: 10.1126/sciadv.aau5363

Cite This Page:

University of Helsinki. "Atmospheric aerosol formation from biogenic vapors is strongly affected by air pollutants." ScienceDaily. ScienceDaily, 14 December 2018. <www.sciencedaily.com/releases/2018/12/181214093814.htm>.
University of Helsinki. (2018, December 14). Atmospheric aerosol formation from biogenic vapors is strongly affected by air pollutants. ScienceDaily. Retrieved March 28, 2024 from www.sciencedaily.com/releases/2018/12/181214093814.htm
University of Helsinki. "Atmospheric aerosol formation from biogenic vapors is strongly affected by air pollutants." ScienceDaily. www.sciencedaily.com/releases/2018/12/181214093814.htm (accessed March 28, 2024).

Explore More

from ScienceDaily

RELATED STORIES